Cationic photoinitiated copolymerization of 1-propenyl-vinyl ether systems
(2002) In European Polymer Journal 38(4). p.655-659- Abstract
A kinetic investigation of the photoinitiated cationic copolymerization of 1-propenyl ethers with vinyl ethers monomers was performed by using FT-IR and 1H-NMR analysis. FT-IR results, obtained in bulk, indicate a higher reactivity of the vinyl ether with respect to the 1-propenyl ether double bond. 1H-NMR analysis, in CDCl3 solution, confirms these results which agree with the literature data concerning monofunctional systems. The properties of the UV cured copolymerization products are investigated by DMTA analysis and discussed on the basis of the kinetic investigation results.
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https://lup.lub.lu.se/record/c1346244-8315-48ec-8aa2-ffd321eca971
- author
- Sangermano, M. ; Malucelli, G. ; Bongiovanni, R. ; Priola, A. ; Annby, U. and Rehnberg, N. LU
- publishing date
- 2002-04
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Cationic photopolymerization, Copolymerization, Propenyl ether, Vinyl ether
- in
- European Polymer Journal
- volume
- 38
- issue
- 4
- pages
- 5 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:0036532911
- ISSN
- 0014-3057
- DOI
- 10.1016/S0014-3057(01)00220-8
- language
- English
- LU publication?
- no
- additional info
- Funding Information: Thanks are due to General Electric and ISP for supplying photoinitiators and monomers. The financial support of Italian MURST PRIN 97 is gratefully acknowledged.
- id
- c1346244-8315-48ec-8aa2-ffd321eca971
- date added to LUP
- 2021-11-23 09:54:57
- date last changed
- 2022-02-02 01:32:02
@article{c1346244-8315-48ec-8aa2-ffd321eca971, abstract = {{<p>A kinetic investigation of the photoinitiated cationic copolymerization of 1-propenyl ethers with vinyl ethers monomers was performed by using FT-IR and <sup>1</sup>H-NMR analysis. FT-IR results, obtained in bulk, indicate a higher reactivity of the vinyl ether with respect to the 1-propenyl ether double bond. <sup>1</sup>H-NMR analysis, in CDCl<sub>3</sub> solution, confirms these results which agree with the literature data concerning monofunctional systems. The properties of the UV cured copolymerization products are investigated by DMTA analysis and discussed on the basis of the kinetic investigation results.</p>}}, author = {{Sangermano, M. and Malucelli, G. and Bongiovanni, R. and Priola, A. and Annby, U. and Rehnberg, N.}}, issn = {{0014-3057}}, keywords = {{Cationic photopolymerization; Copolymerization; Propenyl ether; Vinyl ether}}, language = {{eng}}, number = {{4}}, pages = {{655--659}}, publisher = {{Elsevier}}, series = {{European Polymer Journal}}, title = {{Cationic photoinitiated copolymerization of 1-propenyl-vinyl ether systems}}, url = {{http://dx.doi.org/10.1016/S0014-3057(01)00220-8}}, doi = {{10.1016/S0014-3057(01)00220-8}}, volume = {{38}}, year = {{2002}}, }