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Cationic photoinitiated copolymerization of 1-propenyl-vinyl ether systems

Sangermano, M. ; Malucelli, G. ; Bongiovanni, R. ; Priola, A. ; Annby, U. and Rehnberg, N. LU orcid (2002) In European Polymer Journal 38(4). p.655-659
Abstract

A kinetic investigation of the photoinitiated cationic copolymerization of 1-propenyl ethers with vinyl ethers monomers was performed by using FT-IR and 1H-NMR analysis. FT-IR results, obtained in bulk, indicate a higher reactivity of the vinyl ether with respect to the 1-propenyl ether double bond. 1H-NMR analysis, in CDCl3 solution, confirms these results which agree with the literature data concerning monofunctional systems. The properties of the UV cured copolymerization products are investigated by DMTA analysis and discussed on the basis of the kinetic investigation results.

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author
; ; ; ; and
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Cationic photopolymerization, Copolymerization, Propenyl ether, Vinyl ether
in
European Polymer Journal
volume
38
issue
4
pages
5 pages
publisher
Elsevier
external identifiers
  • scopus:0036532911
ISSN
0014-3057
DOI
10.1016/S0014-3057(01)00220-8
language
English
LU publication?
no
additional info
Funding Information: Thanks are due to General Electric and ISP for supplying photoinitiators and monomers. The financial support of Italian MURST PRIN 97 is gratefully acknowledged.
id
c1346244-8315-48ec-8aa2-ffd321eca971
date added to LUP
2021-11-23 09:54:57
date last changed
2022-02-02 01:32:02
@article{c1346244-8315-48ec-8aa2-ffd321eca971,
  abstract     = {{<p>A kinetic investigation of the photoinitiated cationic copolymerization of 1-propenyl ethers with vinyl ethers monomers was performed by using FT-IR and <sup>1</sup>H-NMR analysis. FT-IR results, obtained in bulk, indicate a higher reactivity of the vinyl ether with respect to the 1-propenyl ether double bond. <sup>1</sup>H-NMR analysis, in CDCl<sub>3</sub> solution, confirms these results which agree with the literature data concerning monofunctional systems. The properties of the UV cured copolymerization products are investigated by DMTA analysis and discussed on the basis of the kinetic investigation results.</p>}},
  author       = {{Sangermano, M. and Malucelli, G. and Bongiovanni, R. and Priola, A. and Annby, U. and Rehnberg, N.}},
  issn         = {{0014-3057}},
  keywords     = {{Cationic photopolymerization; Copolymerization; Propenyl ether; Vinyl ether}},
  language     = {{eng}},
  number       = {{4}},
  pages        = {{655--659}},
  publisher    = {{Elsevier}},
  series       = {{European Polymer Journal}},
  title        = {{Cationic photoinitiated copolymerization of 1-propenyl-vinyl ether systems}},
  url          = {{http://dx.doi.org/10.1016/S0014-3057(01)00220-8}},
  doi          = {{10.1016/S0014-3057(01)00220-8}},
  volume       = {{38}},
  year         = {{2002}},
}