Structure and dynamics of small water clusters, trapped in inert matrices
(2013) In Chemical Physics Letters 581. p.1-9- Abstract
- Recent matrix isolation (p-H-2, Ne, Ar, Kr) studies of water clusters made in Lund are reviewed. Gas phase positions of water cluster bands are estimated from matrix data. Intermolecular spectra of several isotopomers of the water dimer have been obtained, and approximate band strengths have been measured. Acceptor switching of the water dimer has been observed in matrices. A few intermolecular vibrations of (H2O)(3), (D2O)(3), (H2O)(4), and (D2O)(4) have been measured. The pseudorotation of the water trimer is not quenched in matrices, and pentamer pseudorotation appears to be fast as well. Spectra of partially deuterated water tetramers support a rigid cyclic tetramer structure. The hydrogen rotation in p-H-2 may interfere with guest... (More)
- Recent matrix isolation (p-H-2, Ne, Ar, Kr) studies of water clusters made in Lund are reviewed. Gas phase positions of water cluster bands are estimated from matrix data. Intermolecular spectra of several isotopomers of the water dimer have been obtained, and approximate band strengths have been measured. Acceptor switching of the water dimer has been observed in matrices. A few intermolecular vibrations of (H2O)(3), (D2O)(3), (H2O)(4), and (D2O)(4) have been measured. The pseudorotation of the water trimer is not quenched in matrices, and pentamer pseudorotation appears to be fast as well. Spectra of partially deuterated water tetramers support a rigid cyclic tetramer structure. The hydrogen rotation in p-H-2 may interfere with guest vibrations at frequencies near the J = 2 <- J = 0 band of solid parahydrogen. (C) 2013 Elsevier B.V. All rights reserved. (Less)
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https://lup.lub.lu.se/record/4062467
- author
- Ceponkus, J. ; Engdahl, Anders LU ; Uvdal, Per LU and Nelander, Bengt LU
- organization
- publishing date
- 2013
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Physics Letters
- volume
- 581
- pages
- 1 - 9
- publisher
- Elsevier
- external identifiers
-
- wos:000323809900001
- scopus:84881475008
- ISSN
- 0009-2614
- DOI
- 10.1016/j.cplett.2013.06.046
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Max-laboratory (011012005), Chemical Physics (S) (011001060)
- id
- c8aa118a-b46d-478f-828c-08afb7a023e2 (old id 4062467)
- date added to LUP
- 2016-04-01 13:15:49
- date last changed
- 2022-01-27 18:13:16
@article{c8aa118a-b46d-478f-828c-08afb7a023e2,
abstract = {{Recent matrix isolation (p-H-2, Ne, Ar, Kr) studies of water clusters made in Lund are reviewed. Gas phase positions of water cluster bands are estimated from matrix data. Intermolecular spectra of several isotopomers of the water dimer have been obtained, and approximate band strengths have been measured. Acceptor switching of the water dimer has been observed in matrices. A few intermolecular vibrations of (H2O)(3), (D2O)(3), (H2O)(4), and (D2O)(4) have been measured. The pseudorotation of the water trimer is not quenched in matrices, and pentamer pseudorotation appears to be fast as well. Spectra of partially deuterated water tetramers support a rigid cyclic tetramer structure. The hydrogen rotation in p-H-2 may interfere with guest vibrations at frequencies near the J = 2 <- J = 0 band of solid parahydrogen. (C) 2013 Elsevier B.V. All rights reserved.}},
author = {{Ceponkus, J. and Engdahl, Anders and Uvdal, Per and Nelander, Bengt}},
issn = {{0009-2614}},
language = {{eng}},
pages = {{1--9}},
publisher = {{Elsevier}},
series = {{Chemical Physics Letters}},
title = {{Structure and dynamics of small water clusters, trapped in inert matrices}},
url = {{http://dx.doi.org/10.1016/j.cplett.2013.06.046}},
doi = {{10.1016/j.cplett.2013.06.046}},
volume = {{581}},
year = {{2013}},
}