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Palladium(II) Halide Complexes I. Stabilities and Spectra of Palladium(II) Chloro and Bromo Aqua Complexes

Elding, Lars Ivar LU (1972) In Inorganica Chimica Acta 6. p.647-651
Abstract
Stability constants, βn, n = 1, 2, 3, 4, for the chloro and bromo complexes of palladium(II) have been calculated, using a least squares programme, from spectrophotometric measurements at 222, 234.5 and 279 nm (chloride) and at 247, 265, and 332 nm (bromide). The following values of lg(βn/M−n) were obtained: 4.47±0.01, 7.76±0.04, 10.17±0.07, and 11.54±0.09 (chloride) and 5.17±0.02, 9.42±0.04, 12.72±0.06, and 14.94±0.08 (bromide). Spectra of the species PdXn(H2O)4−n2−n, n = 0, 1, 2, 3, 4; X = Cl, Br, have been determined in the wave length region 210 to 600 nm. The temperature was 25.0°C and the ionic medium 1.00 M perchloric acid.
Abstract (Swedish)
Stability constants, βn, n = 1, 2, 3, 4, for the chloro and bromo complexes of palladium(II) have been calculated, using a least squares programme, from spectrophotometric measurements at 222, 234.5 and 279 nm (chloride) and at 247, 265, and 332 nm (bromide). The following values of lg(βn/M−n) were obtained: 4.47±0.01, 7.76±0.04, 10.17±0.07, and 11.54±0.09 (chloride) and 5.17±0.02, 9.42±0.04, 12.72±0.06, and 14.94±0.08 (bromide). Spectra of the species PdXn(H2O)4−n2−n, n = 0, 1, 2, 3, 4; X = Cl, Br, have been determined in the wave length region 210 to 600 nm. The temperature was 25.0°C and the ionic medium 1.00 M perchloric acid.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Palladium(II), Chloride complex, Bromide complex, Stability constants, Absorbance spectra
in
Inorganica Chimica Acta
volume
6
pages
5 pages
publisher
Elsevier
external identifiers
  • scopus:0000848686
ISSN
0020-1693
DOI
10.1016/S0020-1693(00)91874-7
language
English
LU publication?
yes
id
c9c1be9a-4ada-4695-9fcd-f75ad3d71441
date added to LUP
2017-02-19 19:25:12
date last changed
2025-04-04 14:15:21
@article{c9c1be9a-4ada-4695-9fcd-f75ad3d71441,
  abstract     = {{Stability constants, βn, n = 1, 2, 3, 4, for the chloro and bromo complexes of palladium(II) have been calculated, using a least squares programme, from spectrophotometric measurements at 222, 234.5 and 279 nm (chloride) and at 247, 265, and 332 nm (bromide). The following values of lg(βn/M−n) were obtained: 4.47±0.01, 7.76±0.04, 10.17±0.07, and 11.54±0.09 (chloride) and 5.17±0.02, 9.42±0.04, 12.72±0.06, and 14.94±0.08 (bromide). Spectra of the species PdXn(H2O)4−n2−n, n = 0, 1, 2, 3, 4; X = Cl, Br, have been determined in the wave length region 210 to 600 nm. The temperature was 25.0°C and the ionic medium 1.00 M perchloric acid.}},
  author       = {{Elding, Lars Ivar}},
  issn         = {{0020-1693}},
  keywords     = {{Palladium(II); Chloride complex; Bromide complex; Stability constants; Absorbance spectra}},
  language     = {{eng}},
  pages        = {{647--651}},
  publisher    = {{Elsevier}},
  series       = {{Inorganica Chimica Acta}},
  title        = {{Palladium(II) Halide Complexes I. Stabilities and Spectra of Palladium(II) Chloro and Bromo Aqua Complexes}},
  url          = {{http://dx.doi.org/10.1016/S0020-1693(00)91874-7}},
  doi          = {{10.1016/S0020-1693(00)91874-7}},
  volume       = {{6}},
  year         = {{1972}},
}