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Palladium(II) Halide Complexes I. Stabilities and Spectra of Palladium(II) Chloro and Bromo Aqua Complexes

Elding, Lars Ivar LU (1972) In Inorganica Chimica Acta 6. p.647-651
Abstract (Swedish)
Stability constants, βn, n = 1, 2, 3, 4, for the chloro and bromo complexes of palladium(II) have been calculated, using a least squares programme, from spectrophotometric measurements at 222, 234.5 and 279 nm (chloride) and at 247, 265, and 332 nm (bromide). The following values of lg(βn/M−n) were obtained: 4.47±0.01, 7.76±0.04, 10.17±0.07, and 11.54±0.09 (chloride) and 5.17±0.02, 9.42±0.04, 12.72±0.06, and 14.94±0.08 (bromide). Spectra of the species PdXn(H2O)4−n2−n, n = 0, 1, 2, 3, 4; X = Cl, Br, have been determined in the wave length region 210 to 600 nm. The temperature was 25.0°C and the ionic medium 1.00 M perchloric acid.
Abstract
Stability constants, βn, n = 1, 2, 3, 4, for the chloro and bromo complexes of palladium(II) have been calculated, using a least squares programme, from spectrophotometric measurements at 222, 234.5 and 279 nm (chloride) and at 247, 265, and 332 nm (bromide). The following values of lg(βn/M−n) were obtained: 4.47±0.01, 7.76±0.04, 10.17±0.07, and 11.54±0.09 (chloride) and 5.17±0.02, 9.42±0.04, 12.72±0.06, and 14.94±0.08 (bromide). Spectra of the species PdXn(H2O)4−n2−n, n = 0, 1, 2, 3, 4; X = Cl, Br, have been determined in the wave length region 210 to 600 nm. The temperature was 25.0°C and the ionic medium 1.00 M perchloric acid.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Palladium(II), Chloride complex, Bromide complex, Stability constants, Absorbance spectra
in
Inorganica Chimica Acta
volume
6
pages
5 pages
publisher
Elsevier
external identifiers
  • scopus:0000848686
ISSN
0020-1693
DOI
10.1016/S0020-1693(00)91874-7
language
English
LU publication?
yes
id
c9c1be9a-4ada-4695-9fcd-f75ad3d71441
date added to LUP
2017-02-19 19:25:12
date last changed
2017-07-30 05:21:53
@article{c9c1be9a-4ada-4695-9fcd-f75ad3d71441,
  abstract     = {Stability constants, βn, n = 1, 2, 3, 4, for the chloro and bromo complexes of palladium(II) have been calculated, using a least squares programme, from spectrophotometric measurements at 222, 234.5 and 279 nm (chloride) and at 247, 265, and 332 nm (bromide). The following values of lg(βn/M−n) were obtained: 4.47±0.01, 7.76±0.04, 10.17±0.07, and 11.54±0.09 (chloride) and 5.17±0.02, 9.42±0.04, 12.72±0.06, and 14.94±0.08 (bromide). Spectra of the species PdXn(H2O)4−n2−n, n = 0, 1, 2, 3, 4; X = Cl, Br, have been determined in the wave length region 210 to 600 nm. The temperature was 25.0°C and the ionic medium 1.00 M perchloric acid.},
  author       = {Elding, Lars Ivar},
  issn         = {0020-1693},
  keyword      = {Palladium(II),Chloride complex,Bromide complex,Stability constants,Absorbance spectra},
  language     = {eng},
  pages        = {647--651},
  publisher    = {Elsevier},
  series       = {Inorganica Chimica Acta},
  title        = {Palladium(II) Halide Complexes I. Stabilities and Spectra of Palladium(II) Chloro and Bromo Aqua Complexes},
  url          = {http://dx.doi.org/10.1016/S0020-1693(00)91874-7},
  volume       = {6},
  year         = {1972},
}