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Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters

Elding, Lars Ivar LU ; Nordlander, Ebbe LU ; Kiriakidou, Keranio ; Plutino, Maria R. ; Prestopino, Fabio ; Monari, Magda ; Johansson, Maria LU ; Valls, Esteve ; Gobetto, Roberto and Aime, Silvio (1998) In Chemical Communications 1998(24). p.2721-2722
Abstract
Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.
Please use this url to cite or link to this publication:
author
; ; ; ; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Osmium carbonyls, Cluster complex, Addition Reactions, Kinetics, Reaction mechanism
in
Chemical Communications
volume
1998
issue
24
pages
2 pages
publisher
Royal Society of Chemistry
external identifiers
  • scopus:0032556748
ISSN
1364-548X
DOI
10.1039/a807222a
language
English
LU publication?
yes
id
d52ac031-59aa-498e-a769-a1668a23c735
date added to LUP
2016-12-17 19:16:40
date last changed
2025-10-14 09:58:21
@article{d52ac031-59aa-498e-a769-a1668a23c735,
  abstract     = {{Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.}},
  author       = {{Elding, Lars Ivar and Nordlander, Ebbe and Kiriakidou, Keranio and Plutino, Maria R. and Prestopino, Fabio and Monari, Magda and Johansson, Maria and Valls, Esteve and Gobetto, Roberto and Aime, Silvio}},
  issn         = {{1364-548X}},
  keywords     = {{Osmium carbonyls; Cluster complex; Addition Reactions; Kinetics; Reaction mechanism}},
  language     = {{eng}},
  number       = {{24}},
  pages        = {{2721--2722}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Chemical Communications}},
  title        = {{Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters}},
  url          = {{http://dx.doi.org/10.1039/a807222a}},
  doi          = {{10.1039/a807222a}},
  volume       = {{1998}},
  year         = {{1998}},
}