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Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters

Elding, Lars Ivar LU ; Nordlander, Ebbe LU ; Kiriakidou, Keranio; Plutino, Maria R. ; Prestopino, Fabio; Monari, Magda; Johansson, Maria LU ; Valls, Esteve; Gobetto, Roberto and Aime, Silvio (1998) In Chemical Communications 1998(24). p.2721-2722
Abstract
Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Osmium carbonyls, Cluster complex, Addition Reactions, Kinetics, Reaction mechanism
in
Chemical Communications
volume
1998
issue
24
pages
2 pages
publisher
Royal Society of Chemistry
external identifiers
  • scopus:0032556748
ISSN
1364-548X
DOI
10.1039/a807222a
language
English
LU publication?
yes
id
d52ac031-59aa-498e-a769-a1668a23c735
date added to LUP
2016-12-17 19:16:40
date last changed
2017-05-03 17:45:00
@article{d52ac031-59aa-498e-a769-a1668a23c735,
  abstract     = {Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.},
  author       = {Elding, Lars Ivar and Nordlander, Ebbe and Kiriakidou, Keranio and Plutino, Maria R.  and Prestopino, Fabio and Monari, Magda and Johansson, Maria and Valls, Esteve and Gobetto, Roberto and Aime, Silvio},
  issn         = {1364-548X},
  keyword      = {Osmium carbonyls,Cluster complex,Addition Reactions,Kinetics,Reaction mechanism},
  language     = {eng},
  number       = {24},
  pages        = {2721--2722},
  publisher    = {Royal Society of Chemistry},
  series       = {Chemical Communications},
  title        = {Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters},
  url          = {http://dx.doi.org/10.1039/a807222a},
  volume       = {1998},
  year         = {1998},
}