Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters
(1998) In Chemical Communications 1998(24). p.2721-2722- Abstract
- Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/d52ac031-59aa-498e-a769-a1668a23c735
- author
- Elding, Lars Ivar LU ; Nordlander, Ebbe LU ; Kiriakidou, Keranio ; Plutino, Maria R. ; Prestopino, Fabio ; Monari, Magda ; Johansson, Maria LU ; Valls, Esteve ; Gobetto, Roberto and Aime, Silvio
- organization
- publishing date
- 1998
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Osmium carbonyls, Cluster complex, Addition Reactions, Kinetics, Reaction mechanism
- in
- Chemical Communications
- volume
- 1998
- issue
- 24
- pages
- 2 pages
- publisher
- Royal Society of Chemistry
- external identifiers
-
- scopus:0032556748
- ISSN
- 1364-548X
- DOI
- 10.1039/a807222a
- language
- English
- LU publication?
- yes
- id
- d52ac031-59aa-498e-a769-a1668a23c735
- date added to LUP
- 2016-12-17 19:16:40
- date last changed
- 2022-01-30 08:32:46
@article{d52ac031-59aa-498e-a769-a1668a23c735, abstract = {{Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.}}, author = {{Elding, Lars Ivar and Nordlander, Ebbe and Kiriakidou, Keranio and Plutino, Maria R. and Prestopino, Fabio and Monari, Magda and Johansson, Maria and Valls, Esteve and Gobetto, Roberto and Aime, Silvio}}, issn = {{1364-548X}}, keywords = {{Osmium carbonyls; Cluster complex; Addition Reactions; Kinetics; Reaction mechanism}}, language = {{eng}}, number = {{24}}, pages = {{2721--2722}}, publisher = {{Royal Society of Chemistry}}, series = {{Chemical Communications}}, title = {{Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters}}, url = {{http://dx.doi.org/10.1039/a807222a}}, doi = {{10.1039/a807222a}}, volume = {{1998}}, year = {{1998}}, }