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Effect of Alloying with Rare-Earth Metals on the Degradation of Magnesium Alloys Studied Using a Combination of Isothermal Calorimetry and Pressure Measurements

Wadsö, Lars LU ; Hort, Norbert and Orlov, Dmytro LU orcid (2019) Magnesium Technology Symposium held at the TMS Annual Meeting and Exhibition, 2019 In Minerals, Metals and Materials Series p.121-126
Abstract

With all the versatility in structural performance and recent progress in developing magnesium alloys, their Achilles heel remains to be degradation or corrosion property. While applications in mobility demand corrosion protection by all means, bio-medical applications of Mg alloys require well-controlled degradation rates. Meeting these requirements is only possible through the understanding of phenomena on surface–environment interfaces and the characteristics of Mg alloys affecting them. In this study, in situ monitoring during immersion testing along with 3D-optical and scanning-electron microscopy were used for assessing structure-performance characteristics. The effect of alloying with rare-earth metals on the degradation of... (More)

With all the versatility in structural performance and recent progress in developing magnesium alloys, their Achilles heel remains to be degradation or corrosion property. While applications in mobility demand corrosion protection by all means, bio-medical applications of Mg alloys require well-controlled degradation rates. Meeting these requirements is only possible through the understanding of phenomena on surface–environment interfaces and the characteristics of Mg alloys affecting them. In this study, in situ monitoring during immersion testing along with 3D-optical and scanning-electron microscopy were used for assessing structure-performance characteristics. The effect of alloying with rare-earth metals on the degradation of magnesium has been studied in three model alloys Mg–0.8Nd, Mg–0.2Zr and Mg–2.0Gd using a combination of isothermal calorimetry and pressure measurements. The combination appears to be a powerful method to study corrosion of magnesium. The degradation of the Gd-containing alloy is approximately 100 times that of the other two alloys studied and is associated with the release of heat and hydrogen gas in large quantities. Differences in the morphology of corrosion products on Mg–0.8Nd and Mg–0.2Zr alloy surfaces can be associated with minute variations in the degradation process detected by the developed method.

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Please use this url to cite or link to this publication:
author
; and
organization
publishing date
type
Chapter in Book/Report/Conference proceeding
publication status
published
subject
keywords
Degradation, Isothermal calorimetry, Magnesium alloys, Pressure measurements
host publication
Magnesium Technology, 2019
series title
Minerals, Metals and Materials Series
editor
Neelameggham, Neale R. ; Jordon, J. Brian ; Orlov, Dmytro and Joshi, Vineet V.
pages
6 pages
publisher
Springer
conference name
Magnesium Technology Symposium held at the TMS Annual Meeting and Exhibition, 2019
conference location
San Antonio, United States
conference dates
2019-03-10 - 2019-03-14
external identifiers
  • scopus:85064667987
ISSN
2367-1181
2367-1696
ISBN
9783030057886
DOI
10.1007/978-3-030-05789-3_19
project
Topologically designed magnesium alloys for biomedical applications
language
English
LU publication?
yes
id
d56a6f8c-b537-4e82-8335-7c58f9a0bd63
date added to LUP
2019-05-07 08:07:03
date last changed
2024-04-30 06:10:36
@inproceedings{d56a6f8c-b537-4e82-8335-7c58f9a0bd63,
  abstract     = {{<p>With all the versatility in structural performance and recent progress in developing magnesium alloys, their Achilles heel remains to be degradation or corrosion property. While applications in mobility demand corrosion protection by all means, bio-medical applications of Mg alloys require well-controlled degradation rates. Meeting these requirements is only possible through the understanding of phenomena on surface–environment interfaces and the characteristics of Mg alloys affecting them. In this study, in situ monitoring during immersion testing along with 3D-optical and scanning-electron microscopy were used for assessing structure-performance characteristics. The effect of alloying with rare-earth metals on the degradation of magnesium has been studied in three model alloys Mg–0.8Nd, Mg–0.2Zr and Mg–2.0Gd using a combination of isothermal calorimetry and pressure measurements. The combination appears to be a powerful method to study corrosion of magnesium. The degradation of the Gd-containing alloy is approximately 100 times that of the other two alloys studied and is associated with the release of heat and hydrogen gas in large quantities. Differences in the morphology of corrosion products on Mg–0.8Nd and Mg–0.2Zr alloy surfaces can be associated with minute variations in the degradation process detected by the developed method.</p>}},
  author       = {{Wadsö, Lars and Hort, Norbert and Orlov, Dmytro}},
  booktitle    = {{Magnesium Technology, 2019}},
  editor       = {{Neelameggham, Neale R. and Jordon, J. Brian and Orlov, Dmytro and Joshi, Vineet V.}},
  isbn         = {{9783030057886}},
  issn         = {{2367-1181}},
  keywords     = {{Degradation; Isothermal calorimetry; Magnesium alloys; Pressure measurements}},
  language     = {{eng}},
  pages        = {{121--126}},
  publisher    = {{Springer}},
  series       = {{Minerals, Metals and Materials Series}},
  title        = {{Effect of Alloying with Rare-Earth Metals on the Degradation of Magnesium Alloys Studied Using a Combination of Isothermal Calorimetry and Pressure Measurements}},
  url          = {{http://dx.doi.org/10.1007/978-3-030-05789-3_19}},
  doi          = {{10.1007/978-3-030-05789-3_19}},
  year         = {{2019}},
}