EXAFS structural determination of the Pt2(P2O 5H2)44- anion in solution
(2008) In Chimia 62(4). p.287-290- Abstract
We present the first structural determination of the Pt2(P 2O5H2)44- anion in solution by analyzing the extended X-ray absorption fine structure (EXAFS) spectrum of the Pt LIII edge. The data could be fit with a simple model involving single and multiple scattering paths to near and far P-atoms, bridging O-atoms, and the other Pt-atom in the binuclear complex. A Pt-Pt distance of 2.876(28) Å and a Pt-P bond length of 2.32(4) Å are obtained. These values are in line with distances found in previous X-ray diffraction studies. The assignment of the EXAFS spectrum of the Pt 2(P2O5H2)44- anion in its... (More)
We present the first structural determination of the Pt2(P 2O5H2)44- anion in solution by analyzing the extended X-ray absorption fine structure (EXAFS) spectrum of the Pt LIII edge. The data could be fit with a simple model involving single and multiple scattering paths to near and far P-atoms, bridging O-atoms, and the other Pt-atom in the binuclear complex. A Pt-Pt distance of 2.876(28) Å and a Pt-P bond length of 2.32(4) Å are obtained. These values are in line with distances found in previous X-ray diffraction studies. The assignment of the EXAFS spectrum of the Pt 2(P2O5H2)44- anion in its ground state is required for future time-resolved X-ray absorption measurements with the goal of determining the structure and dynamics of the complex in the 1,3A2u excited states.
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- author
- Van Der Veen, Renske M. ; Milne, Christopher J. ; El Nahhas, Amal LU ; Weinstein, Julia A. ; Best, Jonathan ; Borca, Camelia N. ; Bressler, Christian ; Chergui, Majed and Pham, Van-Thai LU
- publishing date
- 2008-05-30
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Diplatinum complexes, EXAFS, Molecular structures
- in
- Chimia
- volume
- 62
- issue
- 4
- pages
- 4 pages
- publisher
- Swiss Chemical Society
- external identifiers
-
- scopus:44349117358
- ISSN
- 0009-4293
- DOI
- 10.2533/chimia.2008.287
- language
- English
- LU publication?
- no
- id
- d70b0c53-6e86-4036-b954-d41ade1540a6
- date added to LUP
- 2019-06-30 10:01:32
- date last changed
- 2022-01-31 22:55:44
@article{d70b0c53-6e86-4036-b954-d41ade1540a6,
abstract = {{<p>We present the first structural determination of the Pt<sub>2</sub>(P <sub>2</sub>O<sub>5</sub>H<sub>2</sub>)<sub>4</sub><sup>4-</sup> anion in solution by analyzing the extended X-ray absorption fine structure (EXAFS) spectrum of the Pt L<sub>III</sub> edge. The data could be fit with a simple model involving single and multiple scattering paths to near and far P-atoms, bridging O-atoms, and the other Pt-atom in the binuclear complex. A Pt-Pt distance of 2.876(28) Å and a Pt-P bond length of 2.32(4) Å are obtained. These values are in line with distances found in previous X-ray diffraction studies. The assignment of the EXAFS spectrum of the Pt <sub>2</sub>(P<sub>2</sub>O<sub>5</sub>H<sub>2</sub>)<sub>4</sub><sup>4-</sup> anion in its ground state is required for future time-resolved X-ray absorption measurements with the goal of determining the structure and dynamics of the complex in the <sup>1,3</sup>A<sub>2u</sub> excited states.</p>}},
author = {{Van Der Veen, Renske M. and Milne, Christopher J. and El Nahhas, Amal and Weinstein, Julia A. and Best, Jonathan and Borca, Camelia N. and Bressler, Christian and Chergui, Majed and Pham, Van-Thai}},
issn = {{0009-4293}},
keywords = {{Diplatinum complexes; EXAFS; Molecular structures}},
language = {{eng}},
month = {{05}},
number = {{4}},
pages = {{287--290}},
publisher = {{Swiss Chemical Society}},
series = {{Chimia}},
title = {{EXAFS structural determination of the Pt<sub>2</sub>(P<sub>2</sub>O <sub>5</sub>H<sub>2</sub>)<sub>4</sub><sup>4-</sup> anion in solution}},
url = {{http://dx.doi.org/10.2533/chimia.2008.287}},
doi = {{10.2533/chimia.2008.287}},
volume = {{62}},
year = {{2008}},
}