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Reaction mechanism of the oxidation of HCl over RuO2(110)

Zweidinger, S. ; Crihan, D. ; Knapp, M. ; Hofmann, J. P. ; Seitsonen, A. P. ; Weststrate, C J ; Lundgren, Edvin LU ; Andersen, Jesper N LU and Over, H. (2008) In Journal of Physical Chemistry C 112(27). p.9966-9969
Abstract
High-resolution core-level shift spectroscopy and temperature-programmed reaction experiments together with density functional theory calculations reveal that the oxidation of HCl with oxygen producing Cl-2 and water proceeds on the chlorine-stabilized RuO2(110)surface via a one-dimensional Langmuir-Hinshelwood mechanism. The recombination of two adjacent chlorine atoms on the catalyst's surface constitutes the rate-determining step in this novel Deacon-like process.
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Physical Chemistry C
volume
112
issue
27
pages
9966 - 9969
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000257335300002
  • scopus:49249112102
ISSN
1932-7447
DOI
10.1021/jp803346q
language
English
LU publication?
yes
id
d82cbc6e-8aae-4615-ac25-1786b26e3173 (old id 1254704)
date added to LUP
2016-04-01 11:58:00
date last changed
2022-02-03 07:41:16
@article{d82cbc6e-8aae-4615-ac25-1786b26e3173,
  abstract     = {{High-resolution core-level shift spectroscopy and temperature-programmed reaction experiments together with density functional theory calculations reveal that the oxidation of HCl with oxygen producing Cl-2 and water proceeds on the chlorine-stabilized RuO2(110)surface via a one-dimensional Langmuir-Hinshelwood mechanism. The recombination of two adjacent chlorine atoms on the catalyst's surface constitutes the rate-determining step in this novel Deacon-like process.}},
  author       = {{Zweidinger, S. and Crihan, D. and Knapp, M. and Hofmann, J. P. and Seitsonen, A. P. and Weststrate, C J and Lundgren, Edvin and Andersen, Jesper N and Over, H.}},
  issn         = {{1932-7447}},
  language     = {{eng}},
  number       = {{27}},
  pages        = {{9966--9969}},
  publisher    = {{The American Chemical Society (ACS)}},
  series       = {{Journal of Physical Chemistry C}},
  title        = {{Reaction mechanism of the oxidation of HCl over RuO2(110)}},
  url          = {{http://dx.doi.org/10.1021/jp803346q}},
  doi          = {{10.1021/jp803346q}},
  volume       = {{112}},
  year         = {{2008}},
}