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Csp3−H Activation without Chelation Assistance in an Iridium Pincer Complex Forming Cyclometallated Products

Ahlstrand, David A. ; Polukeev, Alexey V. LU ; Marcos, Rocío ; Ahlquist, Mårten S G and Wendt, Ola F. LU (2017) In Chemistry - A European Journal 23(8). p.1748-1751
Abstract

Cyclometallation of 8-methylquinoline and 2-(dimethylamino)-pyridine in an iridium-based pincer complex is described. The C−H activation of 2-(dimethylamino)pyridine is not chelation assisted, which has not been described before for Csp3−H bonds in cyclometallation reactions. The mechanism of the cyclometallation of 2-(dimethylamino)pyridine was studied by DFT calculations and kinetic measurements.

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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
cyclometallation, density functional calculations, iridium, pincer complexes, undirected C−H activation
in
Chemistry - A European Journal
volume
23
issue
8
pages
4 pages
publisher
Wiley-Blackwell
external identifiers
  • scopus:85009476799
  • pmid:27982473
  • wos:000395754800003
ISSN
0947-6539
DOI
10.1002/chem.201604469
language
English
LU publication?
yes
id
d9b9915d-5c9f-4d57-9cdb-de87ad146b1b
date added to LUP
2017-03-20 13:33:37
date last changed
2024-04-14 07:30:18
@article{d9b9915d-5c9f-4d57-9cdb-de87ad146b1b,
  abstract     = {{<p>Cyclometallation of 8-methylquinoline and 2-(dimethylamino)-pyridine in an iridium-based pincer complex is described. The C−H activation of 2-(dimethylamino)pyridine is not chelation assisted, which has not been described before for Csp<sup>3</sup>−H bonds in cyclometallation reactions. The mechanism of the cyclometallation of 2-(dimethylamino)pyridine was studied by DFT calculations and kinetic measurements.</p>}},
  author       = {{Ahlstrand, David A. and Polukeev, Alexey V. and Marcos, Rocío and Ahlquist, Mårten S G and Wendt, Ola F.}},
  issn         = {{0947-6539}},
  keywords     = {{cyclometallation; density functional calculations; iridium; pincer complexes; undirected C−H activation}},
  language     = {{eng}},
  number       = {{8}},
  pages        = {{1748--1751}},
  publisher    = {{Wiley-Blackwell}},
  series       = {{Chemistry - A European Journal}},
  title        = {{Csp<sup>3</sup>−H Activation without Chelation Assistance in an Iridium Pincer Complex Forming Cyclometallated Products}},
  url          = {{http://dx.doi.org/10.1002/chem.201604469}},
  doi          = {{10.1002/chem.201604469}},
  volume       = {{23}},
  year         = {{2017}},
}