Lithium Coordination and Mobility in Gel Electrolytes Based on an Acrylate Polymer with Ethylene Oxide Side Chains.
(2003) In Journal of Materials Chemistry 13(4). p.814-817- Abstract
- Multinuclear NMR has been used to investigate the structure and mobility of a series of polymer gel electrolytes. The co-polymers used as matrixes in the gels have acrylate backbones and side chains of ethylene oxide, where the length of the side chains has been varied, while the ratio of acrylate to ethylene oxide has been kept constant. The electrolyte is a mixture of lithium perchlorate and two solvents, ethylene carbonate and gamma butyrolactone. 13C spectra of the different gel electrolytes shows that both solvents interact with the salt, and that the strength of the interaction increases with decreasing length of the polymer side chains. It also appears that the lithium ions show no selectivity between the two types of solvent.... (More)
- Multinuclear NMR has been used to investigate the structure and mobility of a series of polymer gel electrolytes. The co-polymers used as matrixes in the gels have acrylate backbones and side chains of ethylene oxide, where the length of the side chains has been varied, while the ratio of acrylate to ethylene oxide has been kept constant. The electrolyte is a mixture of lithium perchlorate and two solvents, ethylene carbonate and gamma butyrolactone. 13C spectra of the different gel electrolytes shows that both solvents interact with the salt, and that the strength of the interaction increases with decreasing length of the polymer side chains. It also appears that the lithium ions show no selectivity between the two types of solvent. Furthermore, the lithium chemical shift moves progressively upfield with increasing length of the side chains, showing a gradual change in interaction from lithium–solvent to lithium–(ethylene oxide). (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/129498
- author
- Adebahr, J ; Forsyth, M ; MacFarlane, D R ; Gavelin, Patrik LU and Jacobsson, P
- organization
- publishing date
- 2003
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Materials Chemistry
- volume
- 13
- issue
- 4
- pages
- 814 - 817
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000181670900036
- scopus:0037390083
- ISSN
- 1364-5501
- DOI
- 10.1039/b208354j
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- db11acc8-1014-461e-9110-a37aa3372a0a (old id 129498)
- date added to LUP
- 2016-04-01 11:48:51
- date last changed
- 2022-02-03 05:29:46
@article{db11acc8-1014-461e-9110-a37aa3372a0a,
abstract = {{Multinuclear NMR has been used to investigate the structure and mobility of a series of polymer gel electrolytes. The co-polymers used as matrixes in the gels have acrylate backbones and side chains of ethylene oxide, where the length of the side chains has been varied, while the ratio of acrylate to ethylene oxide has been kept constant. The electrolyte is a mixture of lithium perchlorate and two solvents, ethylene carbonate and gamma butyrolactone. 13C spectra of the different gel electrolytes shows that both solvents interact with the salt, and that the strength of the interaction increases with decreasing length of the polymer side chains. It also appears that the lithium ions show no selectivity between the two types of solvent. Furthermore, the lithium chemical shift moves progressively upfield with increasing length of the side chains, showing a gradual change in interaction from lithium–solvent to lithium–(ethylene oxide).}},
author = {{Adebahr, J and Forsyth, M and MacFarlane, D R and Gavelin, Patrik and Jacobsson, P}},
issn = {{1364-5501}},
language = {{eng}},
number = {{4}},
pages = {{814--817}},
publisher = {{Royal Society of Chemistry}},
series = {{Journal of Materials Chemistry}},
title = {{Lithium Coordination and Mobility in Gel Electrolytes Based on an Acrylate Polymer with Ethylene Oxide Side Chains.}},
url = {{http://dx.doi.org/10.1039/b208354j}},
doi = {{10.1039/b208354j}},
volume = {{13}},
year = {{2003}},
}