Radiation induced topotactic [2+2] dimerisation of acrylate derivatives among the layers of a CaFe layered double hydroxide followed by IR spectroscopy
(2013) In Journal of Molecular Structure 1044. p.279-285- Abstract
- Various acrylates [E-phenylpropenoate, E-3(4'-nitrophenyl)propenoate, E-3(2',5'-difluorphenyl)propenoate, E-3(2'-thienyl)propenoate, E-3(4'-imidazolyl)propenoate or E-2,3-dimethylpropenoate] were successfully intercalated into Ca(II)Fe(III) layered double hydroxide (CaFe - LDH) verified by a range of instrumental methods. The possible arrangements for the organic anions were suggested on the basis of basal spacing data, layer thickness and the dimensions of the quantum chemically optimised structures of the acrylate ions. Using the acrylate CaFe LDHs as reactant-filled nanoreactors, photoinitiated topotactic [2 + 2] cyclisation reactions followed by IR spectroscopy could be performed with many representatives [E-phenylpropenoate-,... (More)
- Various acrylates [E-phenylpropenoate, E-3(4'-nitrophenyl)propenoate, E-3(2',5'-difluorphenyl)propenoate, E-3(2'-thienyl)propenoate, E-3(4'-imidazolyl)propenoate or E-2,3-dimethylpropenoate] were successfully intercalated into Ca(II)Fe(III) layered double hydroxide (CaFe - LDH) verified by a range of instrumental methods. The possible arrangements for the organic anions were suggested on the basis of basal spacing data, layer thickness and the dimensions of the quantum chemically optimised structures of the acrylate ions. Using the acrylate CaFe LDHs as reactant-filled nanoreactors, photoinitiated topotactic [2 + 2] cyclisation reactions followed by IR spectroscopy could be performed with many representatives [E-phenylpropenoate-, E-3(4'-nitrophenyl)propenoate-, E-3(2',5'-difluorphenyl)propenoate- or E-3(2'-thienyl)propenoate-CaFe-LDHs] resulting in cyclobutane derivatives within the layers of the host material indicating that there were domains where the intercalated anions were in close proximity to each other and in proper arrangement for the reaction to occur. (C) 2012 Elsevier B.V. All rights reserved. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3975767
- author
- Sranko, D. F. ; Canton, Sophie LU ; Engdahl, Anders LU ; Murath, Sz. ; Kukovecz, A. ; Konya, Z. ; Sipiczki, M. ; Sipos, P. and Palinko, I.
- organization
- publishing date
- 2013
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Intercalation in CaFe layered double hydroxide, Acrylate derivatives, Characterisation, Irradiation induced [2+2] topotactic cyclisation, Selectivity in the confined space
- in
- Journal of Molecular Structure
- volume
- 1044
- pages
- 279 - 285
- publisher
- Elsevier
- external identifiers
-
- wos:000320635200042
- scopus:84878327010
- ISSN
- 0022-2860
- DOI
- 10.1016/j.molstruc.2012.09.063
- language
- English
- LU publication?
- yes
- id
- db28ac3d-6d8e-416d-b49a-64a0283bc3ec (old id 3975767)
- date added to LUP
- 2016-04-01 13:18:04
- date last changed
- 2022-03-29 06:40:56
@article{db28ac3d-6d8e-416d-b49a-64a0283bc3ec, abstract = {{Various acrylates [E-phenylpropenoate, E-3(4'-nitrophenyl)propenoate, E-3(2',5'-difluorphenyl)propenoate, E-3(2'-thienyl)propenoate, E-3(4'-imidazolyl)propenoate or E-2,3-dimethylpropenoate] were successfully intercalated into Ca(II)Fe(III) layered double hydroxide (CaFe - LDH) verified by a range of instrumental methods. The possible arrangements for the organic anions were suggested on the basis of basal spacing data, layer thickness and the dimensions of the quantum chemically optimised structures of the acrylate ions. Using the acrylate CaFe LDHs as reactant-filled nanoreactors, photoinitiated topotactic [2 + 2] cyclisation reactions followed by IR spectroscopy could be performed with many representatives [E-phenylpropenoate-, E-3(4'-nitrophenyl)propenoate-, E-3(2',5'-difluorphenyl)propenoate- or E-3(2'-thienyl)propenoate-CaFe-LDHs] resulting in cyclobutane derivatives within the layers of the host material indicating that there were domains where the intercalated anions were in close proximity to each other and in proper arrangement for the reaction to occur. (C) 2012 Elsevier B.V. All rights reserved.}}, author = {{Sranko, D. F. and Canton, Sophie and Engdahl, Anders and Murath, Sz. and Kukovecz, A. and Konya, Z. and Sipiczki, M. and Sipos, P. and Palinko, I.}}, issn = {{0022-2860}}, keywords = {{Intercalation in CaFe layered double hydroxide; Acrylate derivatives; Characterisation; Irradiation induced [2+2] topotactic cyclisation; Selectivity in the confined space}}, language = {{eng}}, pages = {{279--285}}, publisher = {{Elsevier}}, series = {{Journal of Molecular Structure}}, title = {{Radiation induced topotactic [2+2] dimerisation of acrylate derivatives among the layers of a CaFe layered double hydroxide followed by IR spectroscopy}}, url = {{http://dx.doi.org/10.1016/j.molstruc.2012.09.063}}, doi = {{10.1016/j.molstruc.2012.09.063}}, volume = {{1044}}, year = {{2013}}, }