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Probing RbBr solvation in freestanding sub-2 nm water clusters

Hautala, Lauri; Jänkälä, Kari; Mikkelä, Mikko Heikki LU ; Turunen, Paavo; Prisle, Nønne L.; Patanen, Minna; Tchaplyguine, Maxim LU and Huttula, Marko (2017) In Physical Chemistry Chemical Physics 19(36). p.25158-25167
Abstract

Concentration dependent solvation of RbBr in freestanding sub-2 nm water clusters was studied using core level photoelectron spectroscopy with synchrotron radiation. Spectral features recorded from dilute to saturated clusters indicate that either solvent shared or contact ion pairs are present in increasing amount when the concentration exceeds 2 mol kg-1. For comparison, spectra from anhydrous RbBr clusters are also presented.

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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Physical Chemistry Chemical Physics
volume
19
issue
36
pages
10 pages
publisher
Royal Society of Chemistry
external identifiers
  • scopus:85029798459
  • wos:000411606200079
ISSN
1463-9076
DOI
10.1039/c7cp04398h
language
English
LU publication?
yes
id
df8b8089-9164-4ee1-b3a4-7322efd22fab
date added to LUP
2017-10-10 07:12:03
date last changed
2018-05-29 12:26:22
@article{df8b8089-9164-4ee1-b3a4-7322efd22fab,
  abstract     = {<p>Concentration dependent solvation of RbBr in freestanding sub-2 nm water clusters was studied using core level photoelectron spectroscopy with synchrotron radiation. Spectral features recorded from dilute to saturated clusters indicate that either solvent shared or contact ion pairs are present in increasing amount when the concentration exceeds 2 mol kg<sup>-1</sup>. For comparison, spectra from anhydrous RbBr clusters are also presented.</p>},
  author       = {Hautala, Lauri and Jänkälä, Kari and Mikkelä, Mikko Heikki and Turunen, Paavo and Prisle, Nønne L. and Patanen, Minna and Tchaplyguine, Maxim and Huttula, Marko},
  issn         = {1463-9076},
  language     = {eng},
  number       = {36},
  pages        = {25158--25167},
  publisher    = {Royal Society of Chemistry},
  series       = {Physical Chemistry Chemical Physics},
  title        = {Probing RbBr solvation in freestanding sub-2 nm water clusters},
  url          = {http://dx.doi.org/10.1039/c7cp04398h},
  volume       = {19},
  year         = {2017},
}