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Solution and structural studies of the Cd(II) - Aconitate system

Kostakis, George ; Malandrinos, Gerasimos ; Nordlander, Ebbe LU ; Haukka, Matti and Plakatouras, John C. (2009) In Polyhedron 28(15). p.3227-3234
Abstract
The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Topology, Coordination polymers, Lewis base, Potentiometry, Cadmium complexes
in
Polyhedron
volume
28
issue
15
pages
3227 - 3234
publisher
Elsevier
external identifiers
  • wos:000271144200010
  • scopus:70349448546
ISSN
0277-5387
DOI
10.1016/j.poly.2009.05.008
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
e019bca8-3be3-4c91-9cd5-d503e5fa5ab7 (old id 1505311)
date added to LUP
2016-04-01 14:43:52
date last changed
2022-01-28 02:14:43
@article{e019bca8-3be3-4c91-9cd5-d503e5fa5ab7,
  abstract     = {{The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.}},
  author       = {{Kostakis, George and Malandrinos, Gerasimos and Nordlander, Ebbe and Haukka, Matti and Plakatouras, John C.}},
  issn         = {{0277-5387}},
  keywords     = {{Topology; Coordination polymers; Lewis base; Potentiometry; Cadmium complexes}},
  language     = {{eng}},
  number       = {{15}},
  pages        = {{3227--3234}},
  publisher    = {{Elsevier}},
  series       = {{Polyhedron}},
  title        = {{Solution and structural studies of the Cd(II) - Aconitate system}},
  url          = {{http://dx.doi.org/10.1016/j.poly.2009.05.008}},
  doi          = {{10.1016/j.poly.2009.05.008}},
  volume       = {{28}},
  year         = {{2009}},
}