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Luminescent PhotoCORMs : Enabling/Disabling CO Delivery upon Blue Light Irradiation

Weiss, Vitor C. ; Farias, Giliandro ; Amorim, André L. LU ; Xavier, Fernando R. ; Camargo, Tiago P. ; Bregalda, Mayana B. ; Haukka, Matti ; Nordlander, Ebbe LU ; De Souza, Bernardo and Peralta, Rosely A. (2020) In Inorganic Chemistry 59(18). p.13078-13090
Abstract

The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

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author
; ; ; ; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Inorganic Chemistry
volume
59
issue
18
pages
13 pages
publisher
The American Chemical Society (ACS)
external identifiers
  • pmid:32902965
  • scopus:85091324313
ISSN
0020-1669
DOI
10.1021/acs.inorgchem.0c00638
language
English
LU publication?
yes
id
e0628251-1a04-4609-a25c-290e6f0d6bb3
date added to LUP
2020-10-26 12:24:48
date last changed
2021-06-16 02:11:44
@article{e0628251-1a04-4609-a25c-290e6f0d6bb3,
  abstract     = {<p>The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.</p>},
  author       = {Weiss, Vitor C. and Farias, Giliandro and Amorim, André L. and Xavier, Fernando R. and Camargo, Tiago P. and Bregalda, Mayana B. and Haukka, Matti and Nordlander, Ebbe and De Souza, Bernardo and Peralta, Rosely A.},
  issn         = {0020-1669},
  language     = {eng},
  number       = {18},
  pages        = {13078--13090},
  publisher    = {The American Chemical Society (ACS)},
  series       = {Inorganic Chemistry},
  title        = {Luminescent PhotoCORMs : Enabling/Disabling CO Delivery upon Blue Light Irradiation},
  url          = {http://dx.doi.org/10.1021/acs.inorgchem.0c00638},
  doi          = {10.1021/acs.inorgchem.0c00638},
  volume       = {59},
  year         = {2020},
}