Luminescent PhotoCORMs : Enabling/Disabling CO Delivery upon Blue Light Irradiation
(2020) In Inorganic Chemistry 59(18). p.13078-13090- Abstract
The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/e0628251-1a04-4609-a25c-290e6f0d6bb3
- author
- Weiss, Vitor C. ; Farias, Giliandro ; Amorim, André L. LU ; Xavier, Fernando R. ; Camargo, Tiago P. ; Bregalda, Mayana B. ; Haukka, Matti ; Nordlander, Ebbe LU ; De Souza, Bernardo and Peralta, Rosely A.
- organization
- publishing date
- 2020
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Inorganic Chemistry
- volume
- 59
- issue
- 18
- pages
- 13 pages
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- scopus:85091324313
- pmid:32902965
- ISSN
- 0020-1669
- DOI
- 10.1021/acs.inorgchem.0c00638
- language
- English
- LU publication?
- yes
- id
- e0628251-1a04-4609-a25c-290e6f0d6bb3
- date added to LUP
- 2020-10-26 12:24:48
- date last changed
- 2024-06-27 00:05:33
@article{e0628251-1a04-4609-a25c-290e6f0d6bb3, abstract = {{<p>The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.</p>}}, author = {{Weiss, Vitor C. and Farias, Giliandro and Amorim, André L. and Xavier, Fernando R. and Camargo, Tiago P. and Bregalda, Mayana B. and Haukka, Matti and Nordlander, Ebbe and De Souza, Bernardo and Peralta, Rosely A.}}, issn = {{0020-1669}}, language = {{eng}}, number = {{18}}, pages = {{13078--13090}}, publisher = {{The American Chemical Society (ACS)}}, series = {{Inorganic Chemistry}}, title = {{Luminescent PhotoCORMs : Enabling/Disabling CO Delivery upon Blue Light Irradiation}}, url = {{http://dx.doi.org/10.1021/acs.inorgchem.0c00638}}, doi = {{10.1021/acs.inorgchem.0c00638}}, volume = {{59}}, year = {{2020}}, }