Mechanochemical synthesis and intercalation of Ca(II)Fe(III)-layered double hydroxides
(2016) In Journal of Solid State Chemistry 233. p.236-243- Abstract
A mechanochemical method (grinding the components without added water - dry grinding, followed by further grinding in the presence of minute amount of water or NaOH solution - wet grinding) was used in this work for the preparation and intercalation of CaFe-layered double hydroxides (LDHs). Both the pristine LDHs and the amino acid anion (cystinate and tyrosinate) intercalated varieties were prepared by the two-step grinding procedure in a mixer mill. By systematically changing the conditions of the preparation method, a set of parameters could be determined, which led to the formation of close to phase-pure LDH. The optimisation procedure was also applied for the intercalation processes of the amino acid anions. The resulting materials... (More)
A mechanochemical method (grinding the components without added water - dry grinding, followed by further grinding in the presence of minute amount of water or NaOH solution - wet grinding) was used in this work for the preparation and intercalation of CaFe-layered double hydroxides (LDHs). Both the pristine LDHs and the amino acid anion (cystinate and tyrosinate) intercalated varieties were prepared by the two-step grinding procedure in a mixer mill. By systematically changing the conditions of the preparation method, a set of parameters could be determined, which led to the formation of close to phase-pure LDH. The optimisation procedure was also applied for the intercalation processes of the amino acid anions. The resulting materials were structurally characterised by a range of methods (X-ray diffractometry, scanning electron microscopy, energy dispersive analysis, thermogravimetry, X-ray absorption and infra-red spectroscopies). It was proven that this simple mechanochemical procedure was able to produce complex organic-inorganic nanocomposites: LDHs intercalated with amino acid anions.
(Less)
- author
- Ferencz, Zs ; Szabados, M. ; Varga, G. ; Csendes, Z. ; Kukovecz ; Kónya, Z. ; Carlson, S. LU ; Sipos, P. and Pálinkó, I.
- organization
- publishing date
- 2016-01-01
- type
- Contribution to journal
- publication status
- published
- keywords
- Ca(II)Fe(III)-LDHs, Intercalation, Milling, Nanocomposites with the anions of cystine and tyrosine
- in
- Journal of Solid State Chemistry
- volume
- 233
- pages
- 8 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:84945970595
- wos:000369881200034
- ISSN
- 0022-4596
- DOI
- 10.1016/j.jssc.2015.10.038
- language
- English
- LU publication?
- yes
- id
- e1d695d3-d28d-466c-ab0a-b110ecc5c9bd
- date added to LUP
- 2016-05-04 11:03:58
- date last changed
- 2025-01-12 01:27:32
@article{e1d695d3-d28d-466c-ab0a-b110ecc5c9bd,
abstract = {{<p>A mechanochemical method (grinding the components without added water - dry grinding, followed by further grinding in the presence of minute amount of water or NaOH solution - wet grinding) was used in this work for the preparation and intercalation of CaFe-layered double hydroxides (LDHs). Both the pristine LDHs and the amino acid anion (cystinate and tyrosinate) intercalated varieties were prepared by the two-step grinding procedure in a mixer mill. By systematically changing the conditions of the preparation method, a set of parameters could be determined, which led to the formation of close to phase-pure LDH. The optimisation procedure was also applied for the intercalation processes of the amino acid anions. The resulting materials were structurally characterised by a range of methods (X-ray diffractometry, scanning electron microscopy, energy dispersive analysis, thermogravimetry, X-ray absorption and infra-red spectroscopies). It was proven that this simple mechanochemical procedure was able to produce complex organic-inorganic nanocomposites: LDHs intercalated with amino acid anions.</p>}},
author = {{Ferencz, Zs and Szabados, M. and Varga, G. and Csendes, Z. and Kukovecz and Kónya, Z. and Carlson, S. and Sipos, P. and Pálinkó, I.}},
issn = {{0022-4596}},
keywords = {{Ca(II)Fe(III)-LDHs; Intercalation; Milling; Nanocomposites with the anions of cystine and tyrosine}},
language = {{eng}},
month = {{01}},
pages = {{236--243}},
publisher = {{Elsevier}},
series = {{Journal of Solid State Chemistry}},
title = {{Mechanochemical synthesis and intercalation of Ca(II)Fe(III)-layered double hydroxides}},
url = {{http://dx.doi.org/10.1016/j.jssc.2015.10.038}},
doi = {{10.1016/j.jssc.2015.10.038}},
volume = {{233}},
year = {{2016}},
}