Size selective spectroscopy of Se microclusters
(2012) In Journal of Chemical Physics 137(4).- Abstract
- The electronic structure and photofragmentation in outer and inner valence regions of Se-n (n <= 8) clusters produced by direct vacuum evaporation have been studied with size-selective photoelectron-photoion coincidence technique by using vacuum-ultraviolet synchrotron radiation. The experimental ionization potentials of these clusters were extracted from the partial ion yield measurements. The calculations for the possible geometrical structures of the Se-n microclusters have been executed. The ionization energies of the clusters have been calculated and compared with the experimental results. In addition, theoretical fragment ion appearance energies were estimated. The dissociation energies of Se-n clusters were derived from the... (More)
- The electronic structure and photofragmentation in outer and inner valence regions of Se-n (n <= 8) clusters produced by direct vacuum evaporation have been studied with size-selective photoelectron-photoion coincidence technique by using vacuum-ultraviolet synchrotron radiation. The experimental ionization potentials of these clusters were extracted from the partial ion yield measurements. The calculations for the possible geometrical structures of the Se-n microclusters have been executed. The ionization energies of the clusters have been calculated and compared with the experimental results. In addition, theoretical fragment ion appearance energies were estimated. The dissociation energies of Se-n clusters were derived from the recurrent relation between the gas phase enthalpies of the formation of corresponding cationic clusters and experimental ionization energies. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4737633] (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3059825
- author
- Kooser, K. ; Ha, D. T. ; Itala, E. ; Laksman, Joakim LU ; Urpelainen, Samuli LU and Kukk, E.
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Chemical Physics
- volume
- 137
- issue
- 4
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- wos:000307611500026
- pmid:22852615
- scopus:85024826058
- ISSN
- 0021-9606
- DOI
- 10.1063/1.4737633
- language
- English
- LU publication?
- yes
- id
- ec223bc7-c200-4d18-8cf2-d6f0f9595b57 (old id 3059825)
- date added to LUP
- 2016-04-01 10:05:41
- date last changed
- 2022-02-17 06:30:14
@article{ec223bc7-c200-4d18-8cf2-d6f0f9595b57,
abstract = {{The electronic structure and photofragmentation in outer and inner valence regions of Se-n (n <= 8) clusters produced by direct vacuum evaporation have been studied with size-selective photoelectron-photoion coincidence technique by using vacuum-ultraviolet synchrotron radiation. The experimental ionization potentials of these clusters were extracted from the partial ion yield measurements. The calculations for the possible geometrical structures of the Se-n microclusters have been executed. The ionization energies of the clusters have been calculated and compared with the experimental results. In addition, theoretical fragment ion appearance energies were estimated. The dissociation energies of Se-n clusters were derived from the recurrent relation between the gas phase enthalpies of the formation of corresponding cationic clusters and experimental ionization energies. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4737633]}},
author = {{Kooser, K. and Ha, D. T. and Itala, E. and Laksman, Joakim and Urpelainen, Samuli and Kukk, E.}},
issn = {{0021-9606}},
language = {{eng}},
number = {{4}},
publisher = {{American Institute of Physics (AIP)}},
series = {{Journal of Chemical Physics}},
title = {{Size selective spectroscopy of Se microclusters}},
url = {{https://lup.lub.lu.se/search/files/1555547/3167622.pdf}},
doi = {{10.1063/1.4737633}},
volume = {{137}},
year = {{2012}},
}