Chemistry and indoor air quality in a multi-storey wooden passive (low energy) building: Formation of peroxyacetyl nitrate
(2014) In Indoor & Built Environment 23(3). p.485-496- Abstract
- Indoor air measurements were conducted in one unoccupied apartment of a ‘near-zero-energy’ residential building with a unique, wooden construction. Ozone, NO2, fine particles and volatile organic compounds, formaldehyde, acetaldehyde and peroxyacetyl nitrate (PAN) were measured under ‘as is’ conditions and after intentional intervention by adding ozone to simulate an ambient air ozone episode. Undisturbed concentrations were: O3 5–10?ppb, NO2 5–8?ppb, fine particles 2000–5000?cm?3, formaldehyde 35?±?5?µg/m3, PAN 0.3?ppb. During intervention, O3 was 50–60?ppb, NO2 15–20?ppb, fine particles 20,000–25,000?cm?3, formaldehyde 44?±?2?µg/m3 and PAN 0.7–1?ppb. It was shown that chemical reactions had taken place in the indoor air. Ozone-initiated... (More)
- Indoor air measurements were conducted in one unoccupied apartment of a ‘near-zero-energy’ residential building with a unique, wooden construction. Ozone, NO2, fine particles and volatile organic compounds, formaldehyde, acetaldehyde and peroxyacetyl nitrate (PAN) were measured under ‘as is’ conditions and after intentional intervention by adding ozone to simulate an ambient air ozone episode. Undisturbed concentrations were: O3 5–10?ppb, NO2 5–8?ppb, fine particles 2000–5000?cm?3, formaldehyde 35?±?5?µg/m3, PAN 0.3?ppb. During intervention, O3 was 50–60?ppb, NO2 15–20?ppb, fine particles 20,000–25,000?cm?3, formaldehyde 44?±?2?µg/m3 and PAN 0.7–1?ppb. It was shown that chemical reactions had taken place in the indoor air. Ozone-initiated chemistry produced various aldehydes, PAN and, as a direct response to increased ozone concentrations, also fine particles. Calculations made by a simple model of PAN formation showed that an air change rate of around 0.2?h?1 would provide optimum conditions for PAN formation in a setting comparable to that of the investigated apartment. This air change rate is well below the Swedish national minimum of 0.5?h?1. Further, the calculations show that the non-photochemical PAN formation could be a consequence of mixing ozone and nitrogen dioxide with terpenes and acetaldehyde. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/7515682
- author
- Fischer, Andreas ; Langer, Sarka and Ljungström, Evert
- publishing date
- 2014
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Indoor air chemistry, Low-energy wooden building, Ozone, Peroxyacetyl nitrate, Terpenes, Fine particles, Ventilation
- in
- Indoor & Built Environment
- volume
- 23
- issue
- 3
- pages
- 485 - 496
- publisher
- SAGE Publications
- external identifiers
-
- scopus:84901706216
- ISSN
- 1420-326X
- DOI
- 10.1177/1420326X13487917
- language
- English
- LU publication?
- no
- id
- edb92808-60b5-428f-8cdd-c3352edcd068 (old id 7515682)
- date added to LUP
- 2016-04-04 09:04:57
- date last changed
- 2022-01-29 08:11:59
@article{edb92808-60b5-428f-8cdd-c3352edcd068, abstract = {{Indoor air measurements were conducted in one unoccupied apartment of a ‘near-zero-energy’ residential building with a unique, wooden construction. Ozone, NO2, fine particles and volatile organic compounds, formaldehyde, acetaldehyde and peroxyacetyl nitrate (PAN) were measured under ‘as is’ conditions and after intentional intervention by adding ozone to simulate an ambient air ozone episode. Undisturbed concentrations were: O3 5–10?ppb, NO2 5–8?ppb, fine particles 2000–5000?cm?3, formaldehyde 35?±?5?µg/m3, PAN 0.3?ppb. During intervention, O3 was 50–60?ppb, NO2 15–20?ppb, fine particles 20,000–25,000?cm?3, formaldehyde 44?±?2?µg/m3 and PAN 0.7–1?ppb. It was shown that chemical reactions had taken place in the indoor air. Ozone-initiated chemistry produced various aldehydes, PAN and, as a direct response to increased ozone concentrations, also fine particles. Calculations made by a simple model of PAN formation showed that an air change rate of around 0.2?h?1 would provide optimum conditions for PAN formation in a setting comparable to that of the investigated apartment. This air change rate is well below the Swedish national minimum of 0.5?h?1. Further, the calculations show that the non-photochemical PAN formation could be a consequence of mixing ozone and nitrogen dioxide with terpenes and acetaldehyde.}}, author = {{Fischer, Andreas and Langer, Sarka and Ljungström, Evert}}, issn = {{1420-326X}}, keywords = {{Indoor air chemistry; Low-energy wooden building; Ozone; Peroxyacetyl nitrate; Terpenes; Fine particles; Ventilation}}, language = {{eng}}, number = {{3}}, pages = {{485--496}}, publisher = {{SAGE Publications}}, series = {{Indoor & Built Environment}}, title = {{Chemistry and indoor air quality in a multi-storey wooden passive (low energy) building: Formation of peroxyacetyl nitrate}}, url = {{http://dx.doi.org/10.1177/1420326X13487917}}, doi = {{10.1177/1420326X13487917}}, volume = {{23}}, year = {{2014}}, }