@article{ee90f7c0-3fd1-4ee2-b4d9-f8ee497713f9,
abstract = {{<p><br>
We report the first examples of the carbide ligand in (Cy <br>
<sub>3</sub><br>
P) <br>
<sub>2</sub><br>
Cl <br>
<sub>2</sub><br>
Ru≡C (RuC) developing into a μ <br>
<sub>3</sub><br>
ligand toward metal centers. Conventionally, sterics exclude this coordination mode, but Fe <br>
<sub>2</sub><br>
(CO) <br>
<sub>9</sub><br>
and Co <br>
<sub>2</sub><br>
(CO) <br>
<sub>8</sub><br>
expel bridging CO ligands upon reaction with RuC to form trimetallic (Cy <br>
<sub>3</sub><br>
P) <br>
<sub>2</sub><br>
Cl <br>
<sub>2</sub><br>
Ru=CFe <br>
<sub>2</sub><br>
(CO) <br>
<sub>8</sub><br>
(RuCFe <br>
<sub>2</sub><br>
) and (Cy <br>
<sub>3</sub><br>
P) <br>
<sub>2</sub><br>
Cl <br>
<sub>2</sub><br>
Ru=CCo <br>
<sub>2</sub><br>
(CO) <br>
<sub>7</sub><br>
(RuCCo <br>
<sub>2</sub><br>
) complexes. Thus, the proximity offered by metal-metal associations in bimetallic carbonyl complexes allows the formation of trinuclear carbide complexes as verified by NMR, Mössbauer, and X-ray spectroscopic techniques. <br>
</p>}},
author = {{Reinholdt, Anders and Majer, Sean H. and Gelardi, Rikke M. and Macmillan, Samantha N. and Hill, Anthony F. and Wendt, Ola F. and Lancaster, Kyle M. and Bendix, Jesper}},
issn = {{0020-1669}},
language = {{eng}},
number = {{8}},
pages = {{4812--4819}},
publisher = {{The American Chemical Society (ACS)}},
series = {{Inorganic Chemistry}},
title = {{An Approach to Carbide-Centered Cluster Complexes}},
url = {{http://dx.doi.org/10.1021/acs.inorgchem.8b03222}},
doi = {{10.1021/acs.inorgchem.8b03222}},
volume = {{58}},
year = {{2019}},
}