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Exploring the structure-properties relationship of novel polyamide thin film composite membranes

Lipnizki, Frank LU orcid ; Briceno, Kelly ; Javakhishvili, Irakli ; Fjerbæk, Lene ; Guo, Haofei ; Christensen, Knud Villy ; Norddahl, Birgir and Hvilsed, Søren (2015) Euromembrane 2015
Abstract
Polysulfone (PSf) is a traditional material widely used for manufacturing microfiltration and ultrafiltration membranes by non-solvent induced phase separation (NIPS) process. However, the hydrophobic nature of PSf makes the membranes prone to protein fouling. In order to create non fouling surfaces and further decrease the pore size, the membrane pores can be modified by different strategies as atom transfer radical polymerization [1]. However, these strategies are not adopted by industry due to either cost or technical challenges. This contribution presents the preparation of asymmetric membranes by in situ interfacial polymerization (IP) of thin films (TF) on the PSf support surface in order to form a new polyamide (PA) layer [2]. The... (More)
Polysulfone (PSf) is a traditional material widely used for manufacturing microfiltration and ultrafiltration membranes by non-solvent induced phase separation (NIPS) process. However, the hydrophobic nature of PSf makes the membranes prone to protein fouling. In order to create non fouling surfaces and further decrease the pore size, the membrane pores can be modified by different strategies as atom transfer radical polymerization [1]. However, these strategies are not adopted by industry due to either cost or technical challenges. This contribution presents the preparation of asymmetric membranes by in situ interfacial polymerization (IP) of thin films (TF) on the PSf support surface in order to form a new polyamide (PA) layer [2]. The new PA is hydrophilic and negatively charged, and has prospects in application such as removal of bacteria and heavy metal ions from waste water. The pore size of the barrier layer can be controlled by adjusting the cross-linking degree and chemical composition of the PA network. This work is an attempt to prepare a new PA TF composite membrane and investigate the effect of different amines’ structures on the final membrane properties. Characterization of the PA surface morphology and chemical structure includes scanning electron microscopy, atomic force microscopy, attenuated total reflectance Fourier transform infrared spectroscopy, and streaming potential measurements. Rhodamine B cannot stain the TF composite membrane surface unlike the virgin PSf surface. Furthermore, the water flux decreases from 220 L/h/m²/bar for the PSf membrane to 1.5 L/h/m²/bar for the TF composite membrane. It is therefore concluded that a dense PA TF forms on the porous PSf support after the IP. In order to confirm the antifouling properties, bovine serum albumin/phosphate-bufered saline solution was tested as a model solution to measure flux recovery.

References
[1] Han-Bang Dong, You-Yi Xu, Zhuan Yi, Jun-Li Shi, Modification of polysulfone membranes via surface-initiated atom transfer radical polymerization, Applied Surface Science, 255, (2009), 8860-8866.
[2] Yu Jun Song, Patricia Sun, Lawrence L. Henry, Benhui Sun, Mechanism of structure and performance controlled thin film composite membrane formation via interfacial polymerization process, Journal of Membrane Science, 251, (2005) 67-79.
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author
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organization
publishing date
type
Contribution to conference
publication status
published
subject
keywords
Reverse osmosis, Thin-film membrane
conference name
Euromembrane 2015
conference location
Aachen, Germany
conference dates
2015-09-06 - 2015-09-10
language
English
LU publication?
yes
id
efd49278-88ad-49d5-bc86-c7996c7119cd
date added to LUP
2018-10-15 05:13:09
date last changed
2019-03-08 02:29:55
@misc{efd49278-88ad-49d5-bc86-c7996c7119cd,
  abstract     = {{Polysulfone (PSf) is a traditional material widely used for manufacturing microfiltration and ultrafiltration membranes by non-solvent induced phase separation (NIPS) process. However, the hydrophobic nature of PSf makes the membranes prone to protein fouling. In order to create non fouling surfaces and further decrease the pore size, the membrane pores can be modified by different strategies as atom transfer radical polymerization [1]. However, these strategies are not adopted by industry due to either cost or technical challenges. This contribution presents the preparation of asymmetric membranes by in situ interfacial polymerization (IP) of thin films (TF) on the PSf support surface in order to form a new polyamide (PA) layer [2]. The new PA is hydrophilic and negatively charged, and has prospects in application such as removal of bacteria and heavy metal ions from waste water. The pore size of the barrier layer can be controlled by adjusting the cross-linking degree and chemical composition of the PA network. This work is an attempt to prepare a new PA TF composite membrane and investigate the effect of different amines’ structures on the final membrane properties. Characterization of the PA surface morphology and chemical structure includes scanning electron microscopy, atomic force microscopy, attenuated total reflectance Fourier transform infrared spectroscopy, and streaming potential measurements. Rhodamine B cannot stain the TF composite membrane surface unlike the virgin PSf surface. Furthermore, the water flux decreases from 220 L/h/m²/bar for the PSf membrane to 1.5 L/h/m²/bar for the TF composite membrane. It is therefore concluded that a dense PA TF forms on the porous PSf support after the IP. In order to confirm the antifouling properties, bovine serum albumin/phosphate-bufered saline solution was tested as a model solution to measure flux recovery. <br/><br/>References<br/>[1] Han-Bang Dong, You-Yi Xu, Zhuan Yi, Jun-Li Shi, Modification of polysulfone membranes via surface-initiated atom transfer radical polymerization, Applied Surface Science, 255, (2009), 8860-8866.<br/>[2] Yu Jun Song, Patricia Sun, Lawrence L. Henry, Benhui Sun, Mechanism of structure and performance controlled thin film composite membrane formation via interfacial polymerization process, Journal of Membrane Science, 251, (2005) 67-79.<br/>}},
  author       = {{Lipnizki, Frank and Briceno, Kelly and Javakhishvili, Irakli and Fjerbæk, Lene and Guo, Haofei and Christensen, Knud Villy and Norddahl, Birgir and Hvilsed, Søren}},
  keywords     = {{Reverse osmosis; Thin-film membrane}},
  language     = {{eng}},
  title        = {{Exploring the structure-properties relationship of novel polyamide thin film composite membranes}},
  year         = {{2015}},
}