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Ligand-Promoted [Pd]-Catalyzed α-Alkylation of Ketones through a Borrowing-Hydrogen Approach

Manojveer, Seetharaman LU ; Garg, Nitish K. LU ; Gul, Zarif ; Kanwal, Ayesha ; Goriya, Yogesh LU and Johnson, Magnus T. LU (2023) In ChemistryOpen 12(1).
Abstract

A new class of palladium complexes bearing bidentate 2-hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal-ligand cooperative borrowing-hydrogen (BH) process were demonstrated.

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author
; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
2-hydroxypyridine, borrowing-hydrogen, catalysis, MLC, α-alkylation
in
ChemistryOpen
volume
12
issue
1
article number
e202200245
publisher
John Wiley & Sons Inc.
external identifiers
  • pmid:36592045
  • scopus:85145344073
ISSN
2191-1363
DOI
10.1002/open.202200245
language
English
LU publication?
yes
id
f2cd494e-0902-451a-bf69-9a485623bd96
date added to LUP
2023-02-13 15:36:44
date last changed
2024-03-21 18:03:46
@article{f2cd494e-0902-451a-bf69-9a485623bd96,
  abstract     = {{<p>A new class of palladium complexes bearing bidentate 2-hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal-ligand cooperative borrowing-hydrogen (BH) process were demonstrated.</p>}},
  author       = {{Manojveer, Seetharaman and Garg, Nitish K. and Gul, Zarif and Kanwal, Ayesha and Goriya, Yogesh and Johnson, Magnus T.}},
  issn         = {{2191-1363}},
  keywords     = {{2-hydroxypyridine; borrowing-hydrogen; catalysis; MLC; α-alkylation}},
  language     = {{eng}},
  number       = {{1}},
  publisher    = {{John Wiley & Sons Inc.}},
  series       = {{ChemistryOpen}},
  title        = {{Ligand-Promoted [Pd]-Catalyzed α-Alkylation of Ketones through a Borrowing-Hydrogen Approach}},
  url          = {{http://dx.doi.org/10.1002/open.202200245}},
  doi          = {{10.1002/open.202200245}},
  volume       = {{12}},
  year         = {{2023}},
}