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The coupling between translation and rotation for monomeric water in noble gas matrices.

Ceponkus, J. ; Uvdal, Per LU and Nelander, Bengt LU (2013) In Journal of Chemical Physics 138(24).
Abstract
The rotation of water in noble gas matrices has been studied. It is shown that the rotation-translation coupling model of Friedmann and Kimel predicts rotation line spacings, which are close to the experimental observations for H2O, D2O, and HDO, when gas phase rotation constants are used. The model gives intensity estimates in reasonable agreement with the observations for the local oscillator bands, which accompany the rotation spectrum. It also predicts the intensity variations in the bending region of H2O between neon, argon, and krypton matrices.
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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Chemical Physics
volume
138
issue
24
article number
244305
publisher
American Institute of Physics (AIP)
external identifiers
  • wos:000321148200023
  • pmid:23822242
  • scopus:84879974823
  • pmid:23822242
ISSN
0021-9606
DOI
10.1063/1.4810753
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Max-laboratory (011012005), Chemical Physics (S) (011001060)
id
f345529e-f56d-44b0-b5eb-c1b8497f1077 (old id 3956275)
date added to LUP
2016-04-01 10:55:46
date last changed
2022-04-04 22:30:37
@article{f345529e-f56d-44b0-b5eb-c1b8497f1077,
  abstract     = {{The rotation of water in noble gas matrices has been studied. It is shown that the rotation-translation coupling model of Friedmann and Kimel predicts rotation line spacings, which are close to the experimental observations for H2O, D2O, and HDO, when gas phase rotation constants are used. The model gives intensity estimates in reasonable agreement with the observations for the local oscillator bands, which accompany the rotation spectrum. It also predicts the intensity variations in the bending region of H2O between neon, argon, and krypton matrices.}},
  author       = {{Ceponkus, J. and Uvdal, Per and Nelander, Bengt}},
  issn         = {{0021-9606}},
  language     = {{eng}},
  number       = {{24}},
  publisher    = {{American Institute of Physics (AIP)}},
  series       = {{Journal of Chemical Physics}},
  title        = {{The coupling between translation and rotation for monomeric water in noble gas matrices.}},
  url          = {{http://dx.doi.org/10.1063/1.4810753}},
  doi          = {{10.1063/1.4810753}},
  volume       = {{138}},
  year         = {{2013}},
}