The coupling between translation and rotation for monomeric water in noble gas matrices.
(2013) In Journal of Chemical Physics 138(24).- Abstract
- The rotation of water in noble gas matrices has been studied. It is shown that the rotation-translation coupling model of Friedmann and Kimel predicts rotation line spacings, which are close to the experimental observations for H2O, D2O, and HDO, when gas phase rotation constants are used. The model gives intensity estimates in reasonable agreement with the observations for the local oscillator bands, which accompany the rotation spectrum. It also predicts the intensity variations in the bending region of H2O between neon, argon, and krypton matrices.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3956275
- author
- Ceponkus, J. ; Uvdal, Per LU and Nelander, Bengt LU
- organization
- publishing date
- 2013
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Chemical Physics
- volume
- 138
- issue
- 24
- article number
- 244305
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- wos:000321148200023
- pmid:23822242
- scopus:84879974823
- pmid:23822242
- ISSN
- 0021-9606
- DOI
- 10.1063/1.4810753
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Max-laboratory (011012005), Chemical Physics (S) (011001060)
- id
- f345529e-f56d-44b0-b5eb-c1b8497f1077 (old id 3956275)
- date added to LUP
- 2016-04-01 10:55:46
- date last changed
- 2022-04-04 22:30:37
@article{f345529e-f56d-44b0-b5eb-c1b8497f1077, abstract = {{The rotation of water in noble gas matrices has been studied. It is shown that the rotation-translation coupling model of Friedmann and Kimel predicts rotation line spacings, which are close to the experimental observations for H2O, D2O, and HDO, when gas phase rotation constants are used. The model gives intensity estimates in reasonable agreement with the observations for the local oscillator bands, which accompany the rotation spectrum. It also predicts the intensity variations in the bending region of H2O between neon, argon, and krypton matrices.}}, author = {{Ceponkus, J. and Uvdal, Per and Nelander, Bengt}}, issn = {{0021-9606}}, language = {{eng}}, number = {{24}}, publisher = {{American Institute of Physics (AIP)}}, series = {{Journal of Chemical Physics}}, title = {{The coupling between translation and rotation for monomeric water in noble gas matrices.}}, url = {{http://dx.doi.org/10.1063/1.4810753}}, doi = {{10.1063/1.4810753}}, volume = {{138}}, year = {{2013}}, }