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trans-Di-mu-chloro-bis[(dimethyl sulfoxide-kappa S)phenylplatinum(II)]

Nilsson, Patrik LU and Wendt, Ola LU (2002) In Acta Crystallographica Section E: Structure Reports Online 58(part 11). p.639-640
Abstract
The title compound, [Pt2Cl2(C6H5)2(C2H6OS)2] or [Pt([bold mu]-Cl)Ph(dmso)]2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is centrosymmetric, thus necessitating a trans configuration, with one dmso and one phenyl ligand coordinated to each Pt atom. The two Pt-Cl, the Pt-S and the Pt-C distances are 2.366 (2), 2.475 (2), 2.192 (2) and 1.997 (7) Å, respectively.
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
58
issue
part 11
pages
639 - 640
publisher
International Union of Crystallography
external identifiers
  • wos:000180719300011
ISSN
1600-5368
DOI
10.1107/S1600536802018421
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Inorganic chemistry (ceased) (LUR000010)
id
f5721c2d-7a81-45c2-a31d-0c651c1bac03 (old id 318833)
date added to LUP
2016-04-01 17:14:15
date last changed
2025-04-04 14:15:35
@article{f5721c2d-7a81-45c2-a31d-0c651c1bac03,
  abstract     = {{The title compound, [Pt2Cl2(C6H5)2(C2H6OS)2] or [Pt([bold mu]-Cl)Ph(dmso)]2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is centrosymmetric, thus necessitating a trans configuration, with one dmso and one phenyl ligand coordinated to each Pt atom. The two Pt-Cl, the Pt-S and the Pt-C distances are 2.366 (2), 2.475 (2), 2.192 (2) and 1.997 (7) Å, respectively.}},
  author       = {{Nilsson, Patrik and Wendt, Ola}},
  issn         = {{1600-5368}},
  language     = {{eng}},
  number       = {{part 11}},
  pages        = {{639--640}},
  publisher    = {{International Union of Crystallography}},
  series       = {{Acta Crystallographica Section E: Structure Reports Online}},
  title        = {{trans-Di-mu-chloro-bis[(dimethyl sulfoxide-kappa S)phenylplatinum(II)]}},
  url          = {{http://dx.doi.org/10.1107/S1600536802018421}},
  doi          = {{10.1107/S1600536802018421}},
  volume       = {{58}},
  year         = {{2002}},
}