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The "kER" effect in the double photoionization of H 2

Colgan, J. ; Reddish, T. J. ; Huetz, A. ; Bolognesi, P. ; Avaldi, L. ; Gisselbrecht, M. LU orcid ; Lavollée, M. and Pindzola, M. S. (2008) In Journal of Physics: Conference Series 141.
Abstract

Recent experimental and theoretical work examining the double photoionization of H 2 has uncovered surprising changes in the fully differential cross sections as a function of the kinetic energy released to the protons (which is equivalent to different internuclear separations of the molecule). We describe the recent joint theoretical and experimental investigations which have uncovered the physical reasons for this phenomenon. We show that the observed variations are solely due to the σ component of the polarization vector along the molecular axis. Our conclusions are supported by further investigations of the photoionization of H 2 +, in which similar dramatic variations in the photoelectron... (More)

Recent experimental and theoretical work examining the double photoionization of H 2 has uncovered surprising changes in the fully differential cross sections as a function of the kinetic energy released to the protons (which is equivalent to different internuclear separations of the molecule). We describe the recent joint theoretical and experimental investigations which have uncovered the physical reasons for this phenomenon. We show that the observed variations are solely due to the σ component of the polarization vector along the molecular axis. Our conclusions are supported by further investigations of the photoionization of H 2 +, in which similar dramatic variations in the photoelectron angular distributions for the σ g → σ u transition are found as the internuclear separation is varied. The angular distributions for the σ g → π u transition show little dependence on the internuclear separation.

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publishing date
type
Contribution to journal
publication status
published
in
Journal of Physics: Conference Series
volume
141
article number
012004
publisher
IOP Publishing
external identifiers
  • scopus:65249163449
ISSN
1742-6588
DOI
10.1088/1742-6596/141/1/012004
language
English
LU publication?
no
id
f66c0e79-9cb9-479b-9247-f66cedd0c470
date added to LUP
2017-11-23 14:06:35
date last changed
2022-01-31 00:17:24
@article{f66c0e79-9cb9-479b-9247-f66cedd0c470,
  abstract     = {{<p>Recent experimental and theoretical work examining the double photoionization of H <sub>2</sub> has uncovered surprising changes in the fully differential cross sections as a function of the kinetic energy released to the protons (which is equivalent to different internuclear separations of the molecule). We describe the recent joint theoretical and experimental investigations which have uncovered the physical reasons for this phenomenon. We show that the observed variations are solely due to the <sub>σ</sub> component of the polarization vector along the molecular axis. Our conclusions are supported by further investigations of the photoionization of H <sub>2</sub> <sup>+</sup>, in which similar dramatic variations in the photoelectron angular distributions for the σ <sub>g</sub> → σ <sub>u</sub> transition are found as the internuclear separation is varied. The angular distributions for the σ <sub>g</sub> → π <sub>u</sub> transition show little dependence on the internuclear separation.</p>}},
  author       = {{Colgan, J. and Reddish, T. J. and Huetz, A. and Bolognesi, P. and Avaldi, L. and Gisselbrecht, M. and Lavollée, M. and Pindzola, M. S.}},
  issn         = {{1742-6588}},
  language     = {{eng}},
  publisher    = {{IOP Publishing}},
  series       = {{Journal of Physics: Conference Series}},
  title        = {{The "kER" effect in the double photoionization of H <sub>2</sub>}},
  url          = {{http://dx.doi.org/10.1088/1742-6596/141/1/012004}},
  doi          = {{10.1088/1742-6596/141/1/012004}},
  volume       = {{141}},
  year         = {{2008}},
}