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Solvent-free membrane extraction of volatile fatty acids from acidogenic fermentation

Outram, Victoria LU orcid and Zhang, Yue (2018) In Bioresource Technology 270. p.400-408
Abstract

Diversification of anaerobic digestion into higher value products, namely volatile fatty acids (VFAs), is receiving interest. One of the biggest challenges with this is recovery of the VFAs. Membrane extraction can be used, and a novel process configuration using a non-porous silicone membrane and water for an extractant is proposed here. This process would enable the reduction in the number of downstream unit operations compared to other membrane extraction processes. Selective recovery in favour of longer chain VFAs was demonstrated. Testing with a synthetic solution resulted in an overall mass transfer coefficient of 0.088 μm s −1 for... (More)

Diversification of anaerobic digestion into higher value products, namely volatile fatty acids (VFAs), is receiving interest. One of the biggest challenges with this is recovery of the VFAs. Membrane extraction can be used, and a novel process configuration using a non-porous silicone membrane and water for an extractant is proposed here. This process would enable the reduction in the number of downstream unit operations compared to other membrane extraction processes. Selective recovery in favour of longer chain VFAs was demonstrated. Testing with a synthetic solution resulted in an overall mass transfer coefficient of 0.088 μm s −1 for butyric acid, and 0.157 μm s −1 when fermentation broth was used. This indicates this process is not hindered by fouling, but improved somehow. Although the preliminary economic analysis showed this process to require a larger membrane area compared to porous membrane alternatives, it also has a significantly reduced cost associated with the extractant.

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author
and
publishing date
type
Contribution to journal
publication status
published
keywords
Acidogenic fermentation, In situ product recovery, Membrane extraction, Volatile fatty acids
in
Bioresource Technology
volume
270
pages
9 pages
publisher
Elsevier
external identifiers
  • pmid:30245308
  • scopus:85053850877
ISSN
0960-8524
DOI
10.1016/j.biortech.2018.09.057
language
English
LU publication?
no
additional info
Publisher Copyright: © 2018 Elsevier Ltd
id
f699eb55-214b-481b-b0e6-7acd4882cf28
date added to LUP
2023-05-04 14:17:22
date last changed
2024-05-18 00:49:45
@article{f699eb55-214b-481b-b0e6-7acd4882cf28,
  abstract     = {{<p>                             Diversification of anaerobic digestion into higher value products, namely volatile fatty acids (VFAs), is receiving interest. One of the biggest challenges with this is recovery of the VFAs. Membrane extraction can be used, and a novel process configuration using a non-porous silicone membrane and water for an extractant is proposed here. This process would enable the reduction in the number of downstream unit operations compared to other membrane extraction processes. Selective recovery in favour of longer chain VFAs was demonstrated. Testing with a synthetic solution resulted in an overall mass transfer coefficient of 0.088 μm s                             <sup>−1</sup>                              for butyric acid, and 0.157 μm s                             <sup>−1</sup>                              when fermentation broth was used. This indicates this process is not hindered by fouling, but improved somehow. Although the preliminary economic analysis showed this process to require a larger membrane area compared to porous membrane alternatives, it also has a significantly reduced cost associated with the extractant.</p>}},
  author       = {{Outram, Victoria and Zhang, Yue}},
  issn         = {{0960-8524}},
  keywords     = {{Acidogenic fermentation; In situ product recovery; Membrane extraction; Volatile fatty acids}},
  language     = {{eng}},
  pages        = {{400--408}},
  publisher    = {{Elsevier}},
  series       = {{Bioresource Technology}},
  title        = {{Solvent-free membrane extraction of volatile fatty acids from acidogenic fermentation}},
  url          = {{http://dx.doi.org/10.1016/j.biortech.2018.09.057}},
  doi          = {{10.1016/j.biortech.2018.09.057}},
  volume       = {{270}},
  year         = {{2018}},
}