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Synthetic Approaches to Poly(arylene alkylene) Anion-exchange Membranes

Jannasch, Patric LU orcid (2026) 10th Forum on New Materials
Abstract
Extensive research is currently being conducted to develop anion exchange membranes (AEMs) with high hydroxide conductivity and chemical stability, aiming to increase efficiency and lifetime of alkaline membrane fuel cells, water electrolyzers, and flow batteries. In this context, poly(arylene alkylene)s have recently emerged to offer great opportunities and flexibility to molecularly design and prepare tunable and robust AEMs with high performance and longevity. This class of polymers is prepared by superacid-mediated Friedel-Crafts-type polyhydroxyalkylations, typically involving a ketone or an aldehyde, and an arene such as biphenyl and terphenyl. My research group has over the past 8 years studied poly(arylene alkylene)s and has, for... (More)
Extensive research is currently being conducted to develop anion exchange membranes (AEMs) with high hydroxide conductivity and chemical stability, aiming to increase efficiency and lifetime of alkaline membrane fuel cells, water electrolyzers, and flow batteries. In this context, poly(arylene alkylene)s have recently emerged to offer great opportunities and flexibility to molecularly design and prepare tunable and robust AEMs with high performance and longevity. This class of polymers is prepared by superacid-mediated Friedel-Crafts-type polyhydroxyalkylations, typically involving a ketone or an aldehyde, and an arene such as biphenyl and terphenyl. My research group has over the past 8 years studied poly(arylene alkylene)s and has, for example, reported on the synthesis and properties of different poly(aryl piperidinium) AEMs, demonstrating high alkaline stability and hydroxide conductivity. In the current presentation, I will discuss some of our recent synthetic strategies to tune and improve the preparation, properties, and performance of poly(arylene alkylene) AEMs functionalized with N-alicyclic quaternary ammonium cations. (Less)
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author
organization
publishing date
type
Contribution to conference
publication status
published
subject
conference name
10th Forum on New Materials
conference location
Perugia, Italy
conference dates
2026-06-21 - 2026-06-24
language
English
LU publication?
yes
additional info
Invited lecture. Session: FG-1 New materials synthesis, membrane processing and shaping, characterization. Abstract: FG-1:IL01.
id
f73a7bdd-1c6c-407e-8f2d-e13161eab189
alternative location
https://2026.cimtec-congress.org/symposium-fg-2
date added to LUP
2026-06-24 17:51:44
date last changed
2026-06-25 09:22:46
@misc{f73a7bdd-1c6c-407e-8f2d-e13161eab189,
  abstract     = {{Extensive research is currently being conducted to develop anion exchange membranes (AEMs) with high hydroxide conductivity and chemical stability, aiming to increase efficiency and lifetime of alkaline membrane fuel cells, water electrolyzers, and flow batteries. In this context, poly(arylene alkylene)s have recently emerged to offer great opportunities and flexibility to molecularly design and prepare tunable and robust AEMs with high performance and longevity. This class of polymers is prepared by superacid-mediated Friedel-Crafts-type polyhydroxyalkylations, typically involving a ketone or an aldehyde, and an arene such as biphenyl and terphenyl. My research group has over the past 8 years studied poly(arylene alkylene)s and has, for example, reported on the synthesis and properties of different poly(aryl piperidinium) AEMs, demonstrating high alkaline stability and hydroxide conductivity. In the current presentation, I will discuss some of our recent synthetic strategies to tune and improve the preparation, properties, and performance of poly(arylene alkylene) AEMs functionalized with N-alicyclic quaternary ammonium cations.}},
  author       = {{Jannasch, Patric}},
  language     = {{eng}},
  title        = {{Synthetic Approaches to Poly(arylene alkylene) Anion-exchange Membranes}},
  url          = {{https://2026.cimtec-congress.org/symposium-fg-2}},
  year         = {{2026}},
}