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Use of Heavy Metal Content and Modified Water Quality Index to Assess Groundwater Quality in a Semiarid Area

Kamali Maskooni, Ehsan LU orcid ; Naseri Rad, Mehran LU ; Berndtsson, Ronny LU orcid and Nakagawa, Kei LU orcid (2020) In Water 12(4).
Abstract
Groundwater is a major source of drinking and agricultural water supply in arid and semiarid regions. Poor groundwater quality can be a threat to human health especially when it is combined with hazardous pollutants like heavy metals. In this study, an innovative method involving entropy weighted groundwater quality index for both physicochemical and heavy metal content was used for a semiarid region. The entropy weighted index was used to assess the groundwater’s suitability for drinking and irrigation purposes. Thus, groundwater from 19 sampling sites was used for analyses of physicochemical properties (electrical conductivity—EC, pH, K+, Ca2+, Na+, SO42−, Cl−, HCO3−, TDS, NO3−, F−, biochemical oxygen demand—BOD, dissolved oxygen—DO, and... (More)
Groundwater is a major source of drinking and agricultural water supply in arid and semiarid regions. Poor groundwater quality can be a threat to human health especially when it is combined with hazardous pollutants like heavy metals. In this study, an innovative method involving entropy weighted groundwater quality index for both physicochemical and heavy metal content was used for a semiarid region. The entropy weighted index was used to assess the groundwater’s suitability for drinking and irrigation purposes. Thus, groundwater from 19 sampling sites was used for analyses of physicochemical properties (electrical conductivity—EC, pH, K+, Ca2+, Na+, SO42−, Cl−, HCO3−, TDS, NO3−, F−, biochemical oxygen demand—BOD, dissolved oxygen—DO, and chemical oxygen demand—COD) and heavy metal content (As, Ca, Sb, Se, Zn, Cu, Ba, Mn, and Cr). To evaluate the overall pollution status in the region, heavy metal indices such as the modified heavy metal pollution index (m-HPI), heavy metal evaluation index (HEI), Nemerow index (NeI), and ecological risks of heavy metals (ERI) were calculated and compared. The results showed that Cd concentration plays a significant role in negatively affecting the groundwater quality. Thus, three wells were classified as poor water quality and not acceptable for drinking water supply. The maximum concentration of heavy metals such as Cd, Se, and Sb was higher than permissible limits by the World Health Organization (WHO) standards. However, all wells except one were suitable for agricultural purposes. The advantage of the innovative entropy weighted groundwater quality index for both physicochemical and heavy metal content, is that it permits objectivity when selecting the weights and reduces the error that may be caused by subjectivity. Thus, the new index can be used by groundwater managers and policymakers to better decide the water’s suitability for consumption. (Less)
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author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
heavy metal, water quality index, groundwater pollution, entropy weight
in
Water
volume
12
issue
4
article number
1115
publisher
MDPI AG
external identifiers
  • scopus:85084439230
ISSN
2073-4441
DOI
10.3390/w12041115
language
English
LU publication?
yes
id
f9f20559-c7dc-4212-ab7a-ecce5fd33f31
date added to LUP
2020-04-14 14:33:03
date last changed
2023-10-08 03:09:43
@article{f9f20559-c7dc-4212-ab7a-ecce5fd33f31,
  abstract     = {{Groundwater is a major source of drinking and agricultural water supply in arid and semiarid regions. Poor groundwater quality can be a threat to human health especially when it is combined with hazardous pollutants like heavy metals. In this study, an innovative method involving entropy weighted groundwater quality index for both physicochemical and heavy metal content was used for a semiarid region. The entropy weighted index was used to assess the groundwater’s suitability for drinking and irrigation purposes. Thus, groundwater from 19 sampling sites was used for analyses of physicochemical properties (electrical conductivity—EC, pH, K+, Ca2+, Na+, SO42−, Cl−, HCO3−, TDS, NO3−, F−, biochemical oxygen demand—BOD, dissolved oxygen—DO, and chemical oxygen demand—COD) and heavy metal content (As, Ca, Sb, Se, Zn, Cu, Ba, Mn, and Cr). To evaluate the overall pollution status in the region, heavy metal indices such as the modified heavy metal pollution index (m-HPI), heavy metal evaluation index (HEI), Nemerow index (NeI), and ecological risks of heavy metals (ERI) were calculated and compared. The results showed that Cd concentration plays a significant role in negatively affecting the groundwater quality. Thus, three wells were classified as poor water quality and not acceptable for drinking water supply. The maximum concentration of heavy metals such as Cd, Se, and Sb was higher than permissible limits by the World Health Organization (WHO) standards. However, all wells except one were suitable for agricultural purposes. The advantage of the innovative entropy weighted groundwater quality index for both physicochemical and heavy metal content, is that it permits objectivity when selecting the weights and reduces the error that may be caused by subjectivity. Thus, the new index can be used by groundwater managers and policymakers to better decide the water’s suitability for consumption.}},
  author       = {{Kamali Maskooni, Ehsan and Naseri Rad, Mehran and Berndtsson, Ronny and Nakagawa, Kei}},
  issn         = {{2073-4441}},
  keywords     = {{heavy metal; water quality index; groundwater pollution; entropy weight}},
  language     = {{eng}},
  month        = {{04}},
  number       = {{4}},
  publisher    = {{MDPI AG}},
  series       = {{Water}},
  title        = {{Use of Heavy Metal Content and Modified Water Quality Index to Assess Groundwater Quality in a Semiarid Area}},
  url          = {{http://dx.doi.org/10.3390/w12041115}},
  doi          = {{10.3390/w12041115}},
  volume       = {{12}},
  year         = {{2020}},
}