Synthesis and Spectroscopic Characterisation of a Heterodinuclear Iron(III)-Copper(II) Complex Based on an Asymmetric Dinucleating Ligand System
(2012) In European Journal of Inorganic Chemistry p.4565-4569- Abstract
- The site-directed generation of a heterodinuclear FeIIICuII complex by using a new asymmetric dinucleating ligand FloH is reported. The iron(III) ion is introduced first on the preferential metal-binding site of the ligand that leads to the formation of the thermodynamically favored five-membered chelate rings upon metal-binding. Copper(II) is introduced in the next step. The stepwise metalation strategy reported here may be extended to the preparation of other heterometallic complexes with the view of avoiding a statistical distribution. Such complexes can offer novel spectroscopic properties, electronic structures, and reactivities in comparison to their homometallic analogues.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3244543
- author
- Heims, Florian ; Mereacre, Valeriu ; Ciancetta, Antonella LU ; Mebs, Stefan ; Powell, Annie K. ; Greco, Claudio and Ray, Kallol
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Bioinorganic chemistry, Unsymmetric ligands, Heterometallic complexes, Copper, Iron
- in
- European Journal of Inorganic Chemistry
- issue
- 29
- pages
- 4565 - 4569
- publisher
- John Wiley & Sons Inc.
- external identifiers
-
- wos:000309467600005
- scopus:84867060270
- ISSN
- 1099-0682
- DOI
- 10.1002/ejic.201200156
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Theoretical Chemistry (S) (011001039)
- id
- f9f6789c-083a-49f1-bae7-4a7a92d8b0fd (old id 3244543)
- date added to LUP
- 2016-04-01 10:58:27
- date last changed
- 2023-02-20 07:14:55
@article{f9f6789c-083a-49f1-bae7-4a7a92d8b0fd, abstract = {{The site-directed generation of a heterodinuclear FeIIICuII complex by using a new asymmetric dinucleating ligand FloH is reported. The iron(III) ion is introduced first on the preferential metal-binding site of the ligand that leads to the formation of the thermodynamically favored five-membered chelate rings upon metal-binding. Copper(II) is introduced in the next step. The stepwise metalation strategy reported here may be extended to the preparation of other heterometallic complexes with the view of avoiding a statistical distribution. Such complexes can offer novel spectroscopic properties, electronic structures, and reactivities in comparison to their homometallic analogues.}}, author = {{Heims, Florian and Mereacre, Valeriu and Ciancetta, Antonella and Mebs, Stefan and Powell, Annie K. and Greco, Claudio and Ray, Kallol}}, issn = {{1099-0682}}, keywords = {{Bioinorganic chemistry; Unsymmetric ligands; Heterometallic complexes; Copper; Iron}}, language = {{eng}}, number = {{29}}, pages = {{4565--4569}}, publisher = {{John Wiley & Sons Inc.}}, series = {{European Journal of Inorganic Chemistry}}, title = {{Synthesis and Spectroscopic Characterisation of a Heterodinuclear Iron(III)-Copper(II) Complex Based on an Asymmetric Dinucleating Ligand System}}, url = {{http://dx.doi.org/10.1002/ejic.201200156}}, doi = {{10.1002/ejic.201200156}}, year = {{2012}}, }