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Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

Thapper, Anders ; Sparr, Emma LU ; Johnson, Brian F G ; Lewis, Jack ; Raithby, Paul R and Nordlander, Ebbe LU (2004) In Inorganic Chemistry Communications 7(3). p.443-446
Abstract
The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CH=CH2)3}], [Ru3(CO)10{P(CH2CH=CH2)3}2] and [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] have been prepared; reaction of [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11{P(CH2CH=CH2)3}(PR3)].
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author
; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Cluster, Hemilabile ligand, Allylphosphine
in
Inorganic Chemistry Communications
volume
7
issue
3
pages
443 - 446
publisher
Elsevier
external identifiers
  • wos:000189229800037
  • scopus:1242351272
ISSN
1879-0259
DOI
10.1016/j.inoche.2003.12.032
language
English
LU publication?
yes
id
fac8d727-8ca7-4c77-8916-3cfd8477fcbe (old id 141569)
date added to LUP
2016-04-01 11:48:00
date last changed
2025-10-14 09:36:55
@article{fac8d727-8ca7-4c77-8916-3cfd8477fcbe,
  abstract     = {{The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CH=CH2)3}], [Ru3(CO)10{P(CH2CH=CH2)3}2] and [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] have been prepared; reaction of [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11{P(CH2CH=CH2)3}(PR3)].}},
  author       = {{Thapper, Anders and Sparr, Emma and Johnson, Brian F G and Lewis, Jack and Raithby, Paul R and Nordlander, Ebbe}},
  issn         = {{1879-0259}},
  keywords     = {{Cluster; Hemilabile ligand; Allylphosphine}},
  language     = {{eng}},
  number       = {{3}},
  pages        = {{443--446}},
  publisher    = {{Elsevier}},
  series       = {{Inorganic Chemistry Communications}},
  title        = {{Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster}},
  url          = {{http://dx.doi.org/10.1016/j.inoche.2003.12.032}},
  doi          = {{10.1016/j.inoche.2003.12.032}},
  volume       = {{7}},
  year         = {{2004}},
}