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Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution

Kukushkin, Vadim Yu.; Lövqvist, Karin; Noren, Bertil; Oskarsson, Åke LU and Elding, Lars Ivar LU (1993) In Phosphorus, Sulfur, and Silicon and the Related Elements 75(1-4). p.253-255
Abstract (Swedish)
Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.
Abstract
Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Platinum(II) complexes, Thioethers, Tetraphenylborate, Phenylation , Preparation, Platinum(II), Thioether complex, Phenyl abstraction, Tetraphenyl borate, Synthesis, X-ray diffraction
in
Phosphorus, Sulfur, and Silicon and the Related Elements
volume
75
issue
1-4
pages
3 pages
publisher
Taylor & Francis
external identifiers
  • scopus:0346237217
ISSN
1042-6507
DOI
10.1080/10426509308037400
language
English
LU publication?
yes
id
fc7dda57-2883-419f-be7f-b71ed8d0eac5
date added to LUP
2017-01-07 22:46:35
date last changed
2017-05-29 11:37:39
@article{fc7dda57-2883-419f-be7f-b71ed8d0eac5,
  abstract     = {Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.},
  author       = {Kukushkin, Vadim Yu. and Lövqvist, Karin and Noren, Bertil and Oskarsson, Åke and Elding, Lars Ivar},
  issn         = {1042-6507},
  keyword      = {Platinum(II) complexes,Thioethers,Tetraphenylborate,Phenylation ,Preparation,Platinum(II),Thioether complex,Phenyl abstraction,Tetraphenyl borate,Synthesis,X-ray diffraction},
  language     = {eng},
  number       = {1-4},
  pages        = {253--255},
  publisher    = {Taylor & Francis},
  series       = {Phosphorus, Sulfur, and Silicon and the Related Elements },
  title        = {Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution},
  url          = {http://dx.doi.org/10.1080/10426509308037400},
  volume       = {75},
  year         = {1993},
}