Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution
(1993) In Phosphorus, Sulfur, and Silicon and the Related Elements 75(1-4). p.253-255- Abstract
- Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.
- Abstract (Swedish)
- Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.
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- author
- Kukushkin, Vadim Yu. ; Lövqvist, Karin ; Noren, Bertil ; Oskarsson, Åke LU and Elding, Lars Ivar LU
- organization
- publishing date
- 1993
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Platinum(II) complexes, Thioethers, Tetraphenylborate, Phenylation, Preparation, Platinum(II), Thioether complex, Phenyl abstraction, Tetraphenyl borate, Synthesis, X-ray diffraction
- in
- Phosphorus, Sulfur, and Silicon and the Related Elements
- volume
- 75
- issue
- 1-4
- pages
- 3 pages
- publisher
- Taylor & Francis
- external identifiers
-
- scopus:0346237217
- ISSN
- 1042-6507
- DOI
- 10.1080/10426509308037400
- language
- English
- LU publication?
- yes
- id
- fc7dda57-2883-419f-be7f-b71ed8d0eac5
- date added to LUP
- 2017-01-07 22:46:35
- date last changed
- 2021-01-03 04:06:09
@article{fc7dda57-2883-419f-be7f-b71ed8d0eac5, abstract = {{Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.}}, author = {{Kukushkin, Vadim Yu. and Lövqvist, Karin and Noren, Bertil and Oskarsson, Åke and Elding, Lars Ivar}}, issn = {{1042-6507}}, keywords = {{Platinum(II) complexes; Thioethers; Tetraphenylborate; Phenylation; Preparation; Platinum(II); Thioether complex; Phenyl abstraction; Tetraphenyl borate; Synthesis; X-ray diffraction}}, language = {{eng}}, number = {{1-4}}, pages = {{253--255}}, publisher = {{Taylor & Francis}}, series = {{Phosphorus, Sulfur, and Silicon and the Related Elements}}, title = {{Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution}}, url = {{http://dx.doi.org/10.1080/10426509308037400}}, doi = {{10.1080/10426509308037400}}, volume = {{75}}, year = {{1993}}, }