Electron and Hole Contributions to the Terahertz Photoconductivity of a Conjugated Polymer:Fullerene Blend Identified
Ponseca, Carlito LU ; Nemec, Hynek ; Vukmirovic, Nenad ; Fusco, Sandra ; Wang, Ergang ; Andersson, Mats R. ; Chabera, Pavel LU ; Yartsev, Arkady LU
and Sundström, Villy
LU
(2012)
In The Journal of Physical Chemistry Letters
3(17).
p.2442-2446
- Abstract
- Time-resolved terahertz spectroscopy was employed for the investigation of charge-transport dynamics in benzothiadiazolo-dithiophene polyfluorene ([2,7-(9,9-dioctylfluorene)-alt-S,S-(4',7'-di-2-thieny1-2',1',3'-benzothiadiazole)]) (APFO-3) polymers with various chain lengths and in its monomer form, all blended with an electron acceptor ([6,6]-phenyl-C61-butyric acid methyl ester, PCBM). Upon photo-excitation, charged polaron pairs are created, negative charges are transferred to fullerenes, while positive polarons remain on polymers/monomers. Vastly different hole mobility in polymer and monomer blends allows us to distinguish the hole and electron contributions to the carrier mobility.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3191215
- author
- Ponseca, Carlito
LU
; Nemec, Hynek
; Vukmirovic, Nenad
; Fusco, Sandra
; Wang, Ergang
; Andersson, Mats R.
; Chabera, Pavel
LU
; Yartsev, Arkady
LU
and Sundström, Villy
LU
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- in
- The Journal of Physical Chemistry Letters
- volume
- 3
- issue
- 17
- pages
- 2442 - 2446
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000308342500025
- scopus:84865985528
- pmid:26292130
- ISSN
- 1948-7185
- DOI
- 10.1021/jz301013u
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- fcff360e-f23b-4108-9ad7-2c27088d21ce (old id 3191215)
- date added to LUP
- 2016-04-01 14:41:20
- date last changed
- 2023-09-03 17:57:13
@article{fcff360e-f23b-4108-9ad7-2c27088d21ce,
abstract = {{Time-resolved terahertz spectroscopy was employed for the investigation of charge-transport dynamics in benzothiadiazolo-dithiophene polyfluorene ([2,7-(9,9-dioctylfluorene)-alt-S,S-(4',7'-di-2-thieny1-2',1',3'-benzothiadiazole)]) (APFO-3) polymers with various chain lengths and in its monomer form, all blended with an electron acceptor ([6,6]-phenyl-C61-butyric acid methyl ester, PCBM). Upon photo-excitation, charged polaron pairs are created, negative charges are transferred to fullerenes, while positive polarons remain on polymers/monomers. Vastly different hole mobility in polymer and monomer blends allows us to distinguish the hole and electron contributions to the carrier mobility.}},
author = {{Ponseca, Carlito and Nemec, Hynek and Vukmirovic, Nenad and Fusco, Sandra and Wang, Ergang and Andersson, Mats R. and Chabera, Pavel and Yartsev, Arkady and Sundström, Villy}},
issn = {{1948-7185}},
language = {{eng}},
number = {{17}},
pages = {{2442--2446}},
publisher = {{The American Chemical Society (ACS)}},
series = {{The Journal of Physical Chemistry Letters}},
title = {{Electron and Hole Contributions to the Terahertz Photoconductivity of a Conjugated Polymer:Fullerene Blend Identified}},
url = {{http://dx.doi.org/10.1021/jz301013u}},
doi = {{10.1021/jz301013u}},
volume = {{3}},
year = {{2012}},
}