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Surface-sensitive X-ray diffraction across the pressure gap

Stierle, Andreas; Gustafson, Johan LU and Lundgren, Edvin LU (2017) In Springer Series in Chemical Physics 114. p.59-87
Abstract

In this chapter surface-sensitive X-ray diffraction is introduced as an important crystallographic tool for the investigation of surfaces and nanostructures under high pressure reaction conditions and elevated temperatures which are relevant for industrial catalysis. After the introduction surface-sensitive X-ray diffraction methods are briefly explained and specialized instrumentation developed for the in situ investigation of surfaces and nanostructures across the pressure gap is presented combined with simultaneous measurement of the concentrations of reactants and products. In the following an overview of the experimental results is given: First the (near)-ambient pressure oxidation of 3d, 4d, and 5d transition metals is discussed... (More)

In this chapter surface-sensitive X-ray diffraction is introduced as an important crystallographic tool for the investigation of surfaces and nanostructures under high pressure reaction conditions and elevated temperatures which are relevant for industrial catalysis. After the introduction surface-sensitive X-ray diffraction methods are briefly explained and specialized instrumentation developed for the in situ investigation of surfaces and nanostructures across the pressure gap is presented combined with simultaneous measurement of the concentrations of reactants and products. In the following an overview of the experimental results is given: First the (near)-ambient pressure oxidation of 3d, 4d, and 5d transition metals is discussed which are relevant for oxidation catalysis. Afterwards catalytic reaction experiments in batch mode are reported, followed by an overview of current research using a flow reactor for surface-sensitive X-ray diffraction. Finally a perspective is given for future research directions.

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Please use this url to cite or link to this publication:
author
organization
publishing date
type
Chapter in Book/Report/Conference proceeding
publication status
published
subject
in
Springer Series in Chemical Physics
volume
114
pages
29 pages
publisher
Springer New York LLC
external identifiers
  • scopus:85008157765
ISSN
01726218
DOI
10.1007/978-3-319-44439-0_3
language
English
LU publication?
yes
id
fec72e3f-0499-41bc-a93b-0e74dd58d8a9
date added to LUP
2017-03-16 11:37:56
date last changed
2018-01-07 11:55:56
@inbook{fec72e3f-0499-41bc-a93b-0e74dd58d8a9,
  abstract     = {<p>In this chapter surface-sensitive X-ray diffraction is introduced as an important crystallographic tool for the investigation of surfaces and nanostructures under high pressure reaction conditions and elevated temperatures which are relevant for industrial catalysis. After the introduction surface-sensitive X-ray diffraction methods are briefly explained and specialized instrumentation developed for the in situ investigation of surfaces and nanostructures across the pressure gap is presented combined with simultaneous measurement of the concentrations of reactants and products. In the following an overview of the experimental results is given: First the (near)-ambient pressure oxidation of 3d, 4d, and 5d transition metals is discussed which are relevant for oxidation catalysis. Afterwards catalytic reaction experiments in batch mode are reported, followed by an overview of current research using a flow reactor for surface-sensitive X-ray diffraction. Finally a perspective is given for future research directions.</p>},
  author       = {Stierle, Andreas and Gustafson, Johan and Lundgren, Edvin},
  issn         = {01726218},
  language     = {eng},
  month        = {01},
  pages        = {59--87},
  publisher    = {Springer New York LLC},
  series       = {Springer Series in Chemical Physics},
  title        = {Surface-sensitive X-ray diffraction across the pressure gap},
  url          = {http://dx.doi.org/10.1007/978-3-319-44439-0_3},
  volume       = {114},
  year         = {2017},
}