Autoionisation of super excited states in N2 to the N2+ B state
(2003) In Chemical Physics Letters 372(1-2). p.139-146- Abstract
- Vibrationally resolved N2+ (B–X) (1–2) and (0–1) emission bands were recorded after photoexcitation of N2 in the 20–46 eV energy range. The branching ratio between these transitions reveals strong non-Franck–Condon effects. Ab initio calculations using a configuration interaction method based on Kohn–Sham orbitals indicate that the autoionisation of certain superexcited states is responsible for some structures present in the branching ratio curve.
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https://lup.lub.lu.se/record/1029556
- author
- publishing date
- 2003
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Physics Letters
- volume
- 372
- issue
- 1-2
- pages
- 139 - 146
- publisher
- Elsevier
- external identifiers
-
- scopus:0037461239
- ISSN
- 0009-2614
- DOI
- 10.1016/S0009-2614(03)00380-4
- language
- English
- LU publication?
- no
- id
- cb02cecc-abaa-492a-a17c-63825213aad2 (old id 1029556)
- date added to LUP
- 2016-04-04 09:14:39
- date last changed
- 2022-01-29 08:55:25
@article{cb02cecc-abaa-492a-a17c-63825213aad2, abstract = {{Vibrationally resolved N2+ (B–X) (1–2) and (0–1) emission bands were recorded after photoexcitation of N2 in the 20–46 eV energy range. The branching ratio between these transitions reveals strong non-Franck–Condon effects. Ab initio calculations using a configuration interaction method based on Kohn–Sham orbitals indicate that the autoionisation of certain superexcited states is responsible for some structures present in the branching ratio curve.}}, author = {{Álvarez Ruiz, Jesús and Coreno, Marcelo and Erman, Peter and Kivimäki, Antti and Melero García, Emilio and Prince, Kevin and de Simone, M and Rachlew, Elisabeth and Richter, Robert and Rius i Riu, Jaume and Veseth, Leif}}, issn = {{0009-2614}}, language = {{eng}}, number = {{1-2}}, pages = {{139--146}}, publisher = {{Elsevier}}, series = {{Chemical Physics Letters}}, title = {{Autoionisation of super excited states in N2 to the N2+ B state}}, url = {{http://dx.doi.org/10.1016/S0009-2614(03)00380-4}}, doi = {{10.1016/S0009-2614(03)00380-4}}, volume = {{372}}, year = {{2003}}, }