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Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands

Arunachalampillai, Athimoolam ; Johnson, Magnus LU and Wendt, Ola LU (2008) In Organometallics 27(17). p.4541-4543
Abstract
Treatment of [(COD)PtCl2] with LiN(SiMe3)(2) gives [COD]PtClN(SiMe3)(2) in high yield. This product was fully characterized, including an X-ray structure. From a number of examples it is shown to be a very convenient starting material for the preparation of PXP platinum pincer complexes, giving excellent yields of the cyclometalated product under mild conditions.
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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organometallics
volume
27
issue
17
pages
4541 - 4543
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000258898300033
  • scopus:52649165620
ISSN
1520-6041
DOI
10.1021/om800444g
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
bcfd6ba8-ca72-40cf-987d-5b25998803cd (old id 1247192)
date added to LUP
2016-04-01 12:32:56
date last changed
2022-03-21 05:49:14
@article{bcfd6ba8-ca72-40cf-987d-5b25998803cd,
  abstract     = {{Treatment of [(COD)PtCl2] with LiN(SiMe3)(2) gives [COD]PtClN(SiMe3)(2) in high yield. This product was fully characterized, including an X-ray structure. From a number of examples it is shown to be a very convenient starting material for the preparation of PXP platinum pincer complexes, giving excellent yields of the cyclometalated product under mild conditions.}},
  author       = {{Arunachalampillai, Athimoolam and Johnson, Magnus and Wendt, Ola}},
  issn         = {{1520-6041}},
  language     = {{eng}},
  number       = {{17}},
  pages        = {{4541--4543}},
  publisher    = {{The American Chemical Society (ACS)}},
  series       = {{Organometallics}},
  title        = {{Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands}},
  url          = {{http://dx.doi.org/10.1021/om800444g}},
  doi          = {{10.1021/om800444g}},
  volume       = {{27}},
  year         = {{2008}},
}