Reactivity of palladium(II) methyl complexes towards CO2: formation of carbonate complexes
(2004) In Inorganica Chimica Acta 357(4). p.1295-1298- Abstract
- Treatment of a benzene solution of (tmeda)PdMe2 or (dppe)PdMe2 with carbon dioxide gives the corresponding methyl bicarbonate complex, (L-L)PdMe(O2COH). These were characterised by NMR spectroscopy and elemental analysis. Under strictly dry conditions no reaction was observed. Recrystallisation of the tmeda bicarbonate complex from acetone yields the corresponding eta(2)-carbonate complex, which was characterised by X-ray crystallography. The reaction probably proceeds through attack by free carbonic acid on the dimethyl complex. (C) 2003 Elsevier B.V. All rights reserved.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/141259
- author
- Pushkar, Julia and Wendt, Ola LU
- organization
- publishing date
- 2004
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Palladium complexes, Crystal structures, Carbon dioxide, Carbonate complexes
- in
- Inorganica Chimica Acta
- volume
- 357
- issue
- 4
- pages
- 1295 - 1298
- publisher
- Elsevier
- external identifiers
-
- wos:000220241400046
- scopus:1542316385
- ISSN
- 0020-1693
- DOI
- 10.1016/j.ica.2003.10.027
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- cf2b51a8-4e7d-4251-89ee-323754e46951 (old id 141259)
- date added to LUP
- 2016-04-01 17:13:28
- date last changed
- 2022-03-23 00:11:24
@article{cf2b51a8-4e7d-4251-89ee-323754e46951, abstract = {{Treatment of a benzene solution of (tmeda)PdMe2 or (dppe)PdMe2 with carbon dioxide gives the corresponding methyl bicarbonate complex, (L-L)PdMe(O2COH). These were characterised by NMR spectroscopy and elemental analysis. Under strictly dry conditions no reaction was observed. Recrystallisation of the tmeda bicarbonate complex from acetone yields the corresponding eta(2)-carbonate complex, which was characterised by X-ray crystallography. The reaction probably proceeds through attack by free carbonic acid on the dimethyl complex. (C) 2003 Elsevier B.V. All rights reserved.}}, author = {{Pushkar, Julia and Wendt, Ola}}, issn = {{0020-1693}}, keywords = {{Palladium complexes; Crystal structures; Carbon dioxide; Carbonate complexes}}, language = {{eng}}, number = {{4}}, pages = {{1295--1298}}, publisher = {{Elsevier}}, series = {{Inorganica Chimica Acta}}, title = {{Reactivity of palladium(II) methyl complexes towards CO2: formation of carbonate complexes}}, url = {{http://dx.doi.org/10.1016/j.ica.2003.10.027}}, doi = {{10.1016/j.ica.2003.10.027}}, volume = {{357}}, year = {{2004}}, }