Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2) by weak nucleophiles: Crystal and molecular structure of trans-[PtCl2(eta(2)-CH2=CH2)(MeCN)]
(2009) In Inorganic Chemistry Communications 12(8). p.766-768- Abstract
- Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2), 1, by L in dichloromethane yields trans-[PtCl2(eta(2)-CH2=CH2)(L)] (L = THF, 2, or MeCN, 3) with bridge-splitting equilibrium constants of 0.0289 +/- 0.0007 and 3601 +/- 215 mol(-1) dm(3), respectively, as determined by UV/Vis measurements. The reaction of 3 in MeCN with Cl- is essentially quantitative. The crystal structure of trans-[PtCl2(eta(2)-CH2=CH2)(CH3CN)] is reported. (C) 2009 Elsevier B.V. All rights reserved.
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- author
- Otto, Stefanus ; Roodt, Andreas and Elding, Lars Ivar LU
- organization
- publishing date
- 2009
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Equilibrium constants, Ethene, Platinum, Zeise, Crystal structure
- in
- Inorganic Chemistry Communications
- volume
- 12
- issue
- 8
- pages
- 3 pages
- publisher
- Elsevier
- external identifiers
-
- wos:000269400000018
- scopus:67651222104
- ISSN
- 1879-0259
- DOI
- 10.1016/j.inoche.2009.06.010
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- 238c2fcb-661a-48f5-b59d-28a1592c1c4a (old id 1476306)
- date added to LUP
- 2016-04-01 11:49:22
- date last changed
- 2022-02-25 21:51:45
@article{238c2fcb-661a-48f5-b59d-28a1592c1c4a, abstract = {{Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2), 1, by L in dichloromethane yields trans-[PtCl2(eta(2)-CH2=CH2)(L)] (L = THF, 2, or MeCN, 3) with bridge-splitting equilibrium constants of 0.0289 +/- 0.0007 and 3601 +/- 215 mol(-1) dm(3), respectively, as determined by UV/Vis measurements. The reaction of 3 in MeCN with Cl- is essentially quantitative. The crystal structure of trans-[PtCl2(eta(2)-CH2=CH2)(CH3CN)] is reported. (C) 2009 Elsevier B.V. All rights reserved.}}, author = {{Otto, Stefanus and Roodt, Andreas and Elding, Lars Ivar}}, issn = {{1879-0259}}, keywords = {{Equilibrium constants; Ethene; Platinum; Zeise; Crystal structure}}, language = {{eng}}, number = {{8}}, pages = {{766--768}}, publisher = {{Elsevier}}, series = {{Inorganic Chemistry Communications}}, title = {{Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2) by weak nucleophiles: Crystal and molecular structure of trans-[PtCl2(eta(2)-CH2=CH2)(MeCN)]}}, url = {{http://dx.doi.org/10.1016/j.inoche.2009.06.010}}, doi = {{10.1016/j.inoche.2009.06.010}}, volume = {{12}}, year = {{2009}}, }