Amphiphilic solid polymer electrolytes
Gavelin, Patrik LU ; Ljungbäck, Ronnie ; Jannasch, Patric LU
and Wesslén, Bengt
LU
(2002)
Polymer Electrolytes Symposium 2001 (PES2001)
147(3-4).
p.325-332
- Abstract
- Amphiphilic graft copolymers consisting of methacrylate backbones carrying approximately 48 wt.% of ethylene oxide [(EO)(9) or (EO)(23)] side chains as ionophilic groups and fluorocarbon or hydrocarbon side chains as ionophobic groups were prepared. Solid polymer electrolytes based on the copolymers and lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) were characterized by DSC and the impedance spectroscopy. A maximum ion conductivity of 8 x 10(-5) S cm(-1) at 60 degreesC was found for a polymer electrolyte based on a copolymer having hydrocarbon side chains and (EO)(23) side chains, despite an EO content of only 50 wt.%. No (EO)(n) side chain crystallinity in the electrolytes was detected by calorimetry. The hydrocarbon side chains, on... (More)
- Amphiphilic graft copolymers consisting of methacrylate backbones carrying approximately 48 wt.% of ethylene oxide [(EO)(9) or (EO)(23)] side chains as ionophilic groups and fluorocarbon or hydrocarbon side chains as ionophobic groups were prepared. Solid polymer electrolytes based on the copolymers and lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) were characterized by DSC and the impedance spectroscopy. A maximum ion conductivity of 8 x 10(-5) S cm(-1) at 60 degreesC was found for a polymer electrolyte based on a copolymer having hydrocarbon side chains and (EO)(23) side chains, despite an EO content of only 50 wt.%. No (EO)(n) side chain crystallinity in the electrolytes was detected by calorimetry. The hydrocarbon side chains, on the other hand, were found to form a crystalline phase in the electrolytes. The melting of this phase was not reflected in the shape of the Arrhenius conductivity plot. This indicated that the segmental mobility in the ion conducting phase did not decrease as a result of the presence of the crystalline hydrocarbon phase. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/150805
- author
- Gavelin, Patrik
LU
; Ljungbäck, Ronnie
; Jannasch, Patric
LU
and Wesslén, Bengt
LU
- organization
- publishing date
- 2002
- type
- Chapter in Book/Report/Conference proceeding
- publication status
- published
- subject
- keywords
- Crystallization, Macromonomer polymerization, Graft copolymer, Phase separation, Lithium bis(trifluoromethylsulfonyl)imide, Solid polymer electrolyte
- host publication
- Solid State Ionics
- volume
- 147
- issue
- 3-4
- pages
- 325 - 332
- publisher
- Elsevier
- conference name
- Polymer Electrolytes Symposium 2001 (PES2001)
- conference location
- Noorderwijkerhout, Netherlands
- conference dates
- 2001-05-14 - 2001-05-16
- external identifiers
-
- wos:000175219600017
- scopus:0036534346
- ISSN
- 1872-7689
- 0167-2738
- DOI
- 10.1016/S0167-2738(02)00020-6
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- 67faac96-42e4-41c4-8e04-a359fbf9a47c (old id 150805)
- date added to LUP
- 2016-04-01 11:51:56
- date last changed
- 2024-01-07 23:26:14
@inproceedings{67faac96-42e4-41c4-8e04-a359fbf9a47c,
abstract = {{Amphiphilic graft copolymers consisting of methacrylate backbones carrying approximately 48 wt.% of ethylene oxide [(EO)(9) or (EO)(23)] side chains as ionophilic groups and fluorocarbon or hydrocarbon side chains as ionophobic groups were prepared. Solid polymer electrolytes based on the copolymers and lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) were characterized by DSC and the impedance spectroscopy. A maximum ion conductivity of 8 x 10(-5) S cm(-1) at 60 degreesC was found for a polymer electrolyte based on a copolymer having hydrocarbon side chains and (EO)(23) side chains, despite an EO content of only 50 wt.%. No (EO)(n) side chain crystallinity in the electrolytes was detected by calorimetry. The hydrocarbon side chains, on the other hand, were found to form a crystalline phase in the electrolytes. The melting of this phase was not reflected in the shape of the Arrhenius conductivity plot. This indicated that the segmental mobility in the ion conducting phase did not decrease as a result of the presence of the crystalline hydrocarbon phase.}},
author = {{Gavelin, Patrik and Ljungbäck, Ronnie and Jannasch, Patric and Wesslén, Bengt}},
booktitle = {{Solid State Ionics}},
issn = {{1872-7689}},
keywords = {{Crystallization; Macromonomer polymerization; Graft copolymer; Phase separation; Lithium bis(trifluoromethylsulfonyl)imide; Solid polymer electrolyte}},
language = {{eng}},
number = {{3-4}},
pages = {{325--332}},
publisher = {{Elsevier}},
title = {{Amphiphilic solid polymer electrolytes}},
url = {{http://dx.doi.org/10.1016/S0167-2738(02)00020-6}},
doi = {{10.1016/S0167-2738(02)00020-6}},
volume = {{147}},
year = {{2002}},
}