A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide
(2010) In New Journal of Chemistry 34(10). p.2118-2121- Abstract
- Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1694580
- author
- Jarenmark, Martin LU ; Turitsyna, Elena A. ; Haukka, Matti ; Shteinman, Albert A. and Nordlander, Ebbe LU
- organization
- publishing date
- 2010
- type
- Contribution to journal
- publication status
- published
- subject
- in
- New Journal of Chemistry
- volume
- 34
- issue
- 10
- pages
- 2118 - 2121
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000282219600009
- scopus:77957802674
- ISSN
- 1369-9261
- DOI
- 10.1039/c0nj00293c
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- 8ea962e6-b038-4d36-86eb-5d9a4c57c10d (old id 1694580)
- date added to LUP
- 2016-04-01 10:14:07
- date last changed
- 2022-04-12 03:18:46
@article{8ea962e6-b038-4d36-86eb-5d9a4c57c10d, abstract = {{Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.}}, author = {{Jarenmark, Martin and Turitsyna, Elena A. and Haukka, Matti and Shteinman, Albert A. and Nordlander, Ebbe}}, issn = {{1369-9261}}, language = {{eng}}, number = {{10}}, pages = {{2118--2121}}, publisher = {{Royal Society of Chemistry}}, series = {{New Journal of Chemistry}}, title = {{A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide}}, url = {{http://dx.doi.org/10.1039/c0nj00293c}}, doi = {{10.1039/c0nj00293c}}, volume = {{34}}, year = {{2010}}, }