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A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

Jarenmark, Martin LU ; Turitsyna, Elena A. ; Haukka, Matti ; Shteinman, Albert A. and Nordlander, Ebbe LU (2010) In New Journal of Chemistry 34(10). p.2118-2121
Abstract
Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
New Journal of Chemistry
volume
34
issue
10
pages
2118 - 2121
publisher
Royal Society of Chemistry
external identifiers
  • wos:000282219600009
  • scopus:77957802674
ISSN
1369-9261
DOI
10.1039/c0nj00293c
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
8ea962e6-b038-4d36-86eb-5d9a4c57c10d (old id 1694580)
date added to LUP
2016-04-01 10:14:07
date last changed
2022-04-12 03:18:46
@article{8ea962e6-b038-4d36-86eb-5d9a4c57c10d,
  abstract     = {{Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.}},
  author       = {{Jarenmark, Martin and Turitsyna, Elena A. and Haukka, Matti and Shteinman, Albert A. and Nordlander, Ebbe}},
  issn         = {{1369-9261}},
  language     = {{eng}},
  number       = {{10}},
  pages        = {{2118--2121}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{New Journal of Chemistry}},
  title        = {{A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide}},
  url          = {{http://dx.doi.org/10.1039/c0nj00293c}},
  doi          = {{10.1039/c0nj00293c}},
  volume       = {{34}},
  year         = {{2010}},
}