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Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspi ro[5.5]undecane

Mohlmann, Lennart ; Wendt, Ola LU and Johnson, Magnus LU (2011) In Acta Crystallographica Section E: Structure Reports Online 67(Pt 6). p.719-720
Abstract
The AuI atom in the title compound, [Au(C21H24N2)(2)](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)degrees. In the crystal, the components are linked by weak C-H...O hydrogen bonds.
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author
; and
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publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
67
issue
Pt 6
pages
719 - 720
publisher
International Union of Crystallography
external identifiers
  • wos:000291215800054
  • scopus:79958019246
  • pmid:21754618
  • pmid:21754618
ISSN
1600-5368
DOI
10.1107/S1600536811016357
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
0447a0ef-fe38-425a-b754-18602caf9488 (old id 1985689)
date added to LUP
2016-04-01 12:59:30
date last changed
2022-01-27 08:40:32
@article{0447a0ef-fe38-425a-b754-18602caf9488,
  abstract     = {{The AuI atom in the title compound, [Au(C21H24N2)(2)](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)degrees. In the crystal, the components are linked by weak C-H...O hydrogen bonds.}},
  author       = {{Mohlmann, Lennart and Wendt, Ola and Johnson, Magnus}},
  issn         = {{1600-5368}},
  language     = {{eng}},
  number       = {{Pt 6}},
  pages        = {{719--720}},
  publisher    = {{International Union of Crystallography}},
  series       = {{Acta Crystallographica Section E: Structure Reports Online}},
  title        = {{Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspi ro[5.5]undecane}},
  url          = {{http://dx.doi.org/10.1107/S1600536811016357}},
  doi          = {{10.1107/S1600536811016357}},
  volume       = {{67}},
  year         = {{2011}},
}