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Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster

Jalilian, Ehsan and Lidin, Sven LU (2011) In Solid State Sciences 13(4). p.768-772
Abstract
Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Copper(I) iodide cluster, Structure
in
Solid State Sciences
volume
13
issue
4
pages
768 - 772
publisher
Elsevier
external identifiers
  • wos:000289965900014
  • scopus:79953057620
ISSN
1873-3085
DOI
10.1016/j.solidstatesciences.2010.03.019
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
id
a8f4e0a2-a713-48c3-b2f9-3c968eda43d2 (old id 1987068)
date added to LUP
2016-04-01 10:07:17
date last changed
2022-01-25 19:57:16
@article{a8f4e0a2-a713-48c3-b2f9-3c968eda43d2,
  abstract     = {{Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.}},
  author       = {{Jalilian, Ehsan and Lidin, Sven}},
  issn         = {{1873-3085}},
  keywords     = {{Copper(I) iodide cluster; Structure}},
  language     = {{eng}},
  number       = {{4}},
  pages        = {{768--772}},
  publisher    = {{Elsevier}},
  series       = {{Solid State Sciences}},
  title        = {{Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster}},
  url          = {{http://dx.doi.org/10.1016/j.solidstatesciences.2010.03.019}},
  doi          = {{10.1016/j.solidstatesciences.2010.03.019}},
  volume       = {{13}},
  year         = {{2011}},
}