Skip to main content

Lund University Publications

LUND UNIVERSITY LIBRARIES

Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands

Behrens, A ; Behrens, U ; Nordlander, Ebbe LU ; Bader, C and Rehder, D (2005) In Inorganica Chimica Acta 358(6). p.1970-1974
Abstract
Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.
Please use this url to cite or link to this publication:
author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
molybdopterin, molybdenum complexes, thiofunctional ligands, oxotransferases
in
Inorganica Chimica Acta
volume
358
issue
6
pages
1970 - 1974
publisher
Elsevier
external identifiers
  • wos:000227975700028
  • scopus:14844298767
ISSN
0020-1693
DOI
10.1016/j.ica.2004.12.039
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
3cf87e5d-c9b2-4358-b7b5-11eab2ac472b (old id 247090)
date added to LUP
2016-04-01 16:11:32
date last changed
2022-01-28 18:01:12
@article{3cf87e5d-c9b2-4358-b7b5-11eab2ac472b,
  abstract     = {{Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.}},
  author       = {{Behrens, A and Behrens, U and Nordlander, Ebbe and Bader, C and Rehder, D}},
  issn         = {{0020-1693}},
  keywords     = {{molybdopterin; molybdenum complexes; thiofunctional ligands; oxotransferases}},
  language     = {{eng}},
  number       = {{6}},
  pages        = {{1970--1974}},
  publisher    = {{Elsevier}},
  series       = {{Inorganica Chimica Acta}},
  title        = {{Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands}},
  url          = {{http://dx.doi.org/10.1016/j.ica.2004.12.039}},
  doi          = {{10.1016/j.ica.2004.12.039}},
  volume       = {{358}},
  year         = {{2005}},
}