Carboxylation of pincer PCP platinum methoxide complexes under formation of metalla carbonates
(2012) In Polyhedron 32(1). p.24-29- Abstract
- The ligand 2,6-bis[(diphenylphosphino)methyl]benzene ((PCP)H) was prepared and characterised in an improved manner. With platinum it forms the complex (PCP)PtOTf which reacts with sodium methoxide to give (PCP)PtOMe as the major product together with a small amount of [(PCP)Pt](2)-mu-H. The platinum methoxide reacts with carbon dioxide to give (PCP)PtO(CO)OMe. Also the dinuclear [(PCP)Pt](2)(mu-O(CO)OMe) is formed in this reaction if (PCP)PtOTf is present. The crystal structures for [(PCP)PtOH2]OTf, PCP)PtOMe, [(PCP)Pt](2)-mu-H and [(PCP)Pt](2)(mu-O(CO)OMe) are reported. (c) 2011 Elsevier Ltd. All rights reserved.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2517468
- author
- Arunachalampillai, Athimoolam ; Loganathan, Nagarajan LU and Wendt, Ola LU
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- complexes, Carbonate, Alkoxide complexes, Pincer ligands, Carbon dioxide, Platinum
- in
- Polyhedron
- volume
- 32
- issue
- 1
- pages
- 24 - 29
- publisher
- Elsevier
- external identifiers
-
- wos:000300815500004
- scopus:84855288069
- ISSN
- 0277-5387
- DOI
- 10.1016/j.poly.2011.08.028
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- 7b5bd9f2-3ac5-46b1-9baa-b40d7294f674 (old id 2517468)
- date added to LUP
- 2016-04-01 14:57:30
- date last changed
- 2022-04-22 06:03:47
@article{7b5bd9f2-3ac5-46b1-9baa-b40d7294f674, abstract = {{The ligand 2,6-bis[(diphenylphosphino)methyl]benzene ((PCP)H) was prepared and characterised in an improved manner. With platinum it forms the complex (PCP)PtOTf which reacts with sodium methoxide to give (PCP)PtOMe as the major product together with a small amount of [(PCP)Pt](2)-mu-H. The platinum methoxide reacts with carbon dioxide to give (PCP)PtO(CO)OMe. Also the dinuclear [(PCP)Pt](2)(mu-O(CO)OMe) is formed in this reaction if (PCP)PtOTf is present. The crystal structures for [(PCP)PtOH2]OTf, PCP)PtOMe, [(PCP)Pt](2)-mu-H and [(PCP)Pt](2)(mu-O(CO)OMe) are reported. (c) 2011 Elsevier Ltd. All rights reserved.}}, author = {{Arunachalampillai, Athimoolam and Loganathan, Nagarajan and Wendt, Ola}}, issn = {{0277-5387}}, keywords = {{complexes; Carbonate; Alkoxide complexes; Pincer ligands; Carbon dioxide; Platinum}}, language = {{eng}}, number = {{1}}, pages = {{24--29}}, publisher = {{Elsevier}}, series = {{Polyhedron}}, title = {{Carboxylation of pincer PCP platinum methoxide complexes under formation of metalla carbonates}}, url = {{http://dx.doi.org/10.1016/j.poly.2011.08.028}}, doi = {{10.1016/j.poly.2011.08.028}}, volume = {{32}}, year = {{2012}}, }