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Picosecond time-resolved X-ray emission spectroscopy : Ultrafast spin-state determination in an iron complex

Vankó, György ; Glatzel, Pieter ; Abela, Rafael ; Grolimund, Daniel ; Borca, Camelia N. ; Johnson, Steven L. ; Milne, Christopher J. ; Bressler, Christian and Pham, Van-Thai LU (2010) In Angewandte Chemie - International Edition 49(34). p.5910-5912
Abstract

(Figure Presented) Ultrafast spin probe: A short-lived transient species of light-excited [Fe(bpy) 3 ] 2+ (bpy = 2,2′-bipyridine) shows geometry variations that correspond to excitation to a high-spin state, in which the spin momentum of Fe" has now been directly determined to be S = 2 by spin-sensitive ultrafast X-ray emission spectroscopy.

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author
; ; ; ; ; ; ; and
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Femtochemistry, Iron, Spin crossover, Time-resolved spectroscopy, X-ray emission spectroscopy
in
Angewandte Chemie - International Edition
volume
49
issue
34
pages
3 pages
publisher
John Wiley & Sons Inc.
external identifiers
  • scopus:77955583341
ISSN
1433-7851
DOI
10.1002/anie.201000844
language
English
LU publication?
no
id
2b5bbeaf-238c-44f7-9670-f1d9fc404ffc
date added to LUP
2019-06-30 09:55:55
date last changed
2022-03-18 02:48:39
@article{2b5bbeaf-238c-44f7-9670-f1d9fc404ffc,
  abstract     = {{<p>                            (Figure Presented) Ultrafast spin probe: A short-lived transient species of light-excited [Fe(bpy)                            <sub>3</sub>                            ]                            <sup>2+</sup>                             (bpy = 2,2′-bipyridine) shows geometry variations that correspond to excitation to a high-spin state, in which the spin momentum of Fe" has now been directly determined to be S = 2 by spin-sensitive ultrafast X-ray emission spectroscopy.</p>}},
  author       = {{Vankó, György and Glatzel, Pieter and Abela, Rafael and Grolimund, Daniel and Borca, Camelia N. and Johnson, Steven L. and Milne, Christopher J. and Bressler, Christian and Pham, Van-Thai}},
  issn         = {{1433-7851}},
  keywords     = {{Femtochemistry; Iron; Spin crossover; Time-resolved spectroscopy; X-ray emission spectroscopy}},
  language     = {{eng}},
  month        = {{08}},
  number       = {{34}},
  pages        = {{5910--5912}},
  publisher    = {{John Wiley & Sons Inc.}},
  series       = {{Angewandte Chemie - International Edition}},
  title        = {{Picosecond time-resolved X-ray emission spectroscopy : Ultrafast spin-state determination in an iron complex}},
  url          = {{http://dx.doi.org/10.1002/anie.201000844}},
  doi          = {{10.1002/anie.201000844}},
  volume       = {{49}},
  year         = {{2010}},
}