Selective reduction of nitroaromatic compounds on silver nanoparticles by visible light
(2012) In Journal of Raman Spectroscopy 43(8). p.1024-1028- Abstract
- For the first time, we report experimentally and theoretically that nitroaromatic compounds, 2,4-dinitrobenzenethiol and 4-chloro-2-nitrobenzenethiol, on silver sols can be selectively reduced to 2-amino-4-nitrobenzenethiol and 2-amino-4-chlorobenzenethiol simply by irradiating with a visible light in ambient conditions, and the selective photoreduction is a very facile process. The results of quantum chemical calculations are in good agreement with our experimental data. Copyright (c) 2012 John Wiley & Sons, Ltd.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3059769
- author
- Xia, Lixin ; Hu, Xinhu ; Sun, Mengtao ; Li, Jushi ; Yang, Donghui ; Wang, Xiaofang and Xu, Hongxing LU
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- 2, 4-dinitrobenzenethiol, 4-chloro-2-nitrobenzenethiol, silver colloids, surface-enhanced Raman scattering spectroscopy, selective photoreduction
- in
- Journal of Raman Spectroscopy
- volume
- 43
- issue
- 8
- pages
- 1024 - 1028
- publisher
- John Wiley & Sons Inc.
- external identifiers
-
- wos:000307550100010
- scopus:84865172776
- ISSN
- 1097-4555
- DOI
- 10.1002/jrs.3143
- language
- English
- LU publication?
- yes
- id
- a6733874-1624-48c1-87db-95112e5f4b0f (old id 3059769)
- date added to LUP
- 2016-04-01 14:39:54
- date last changed
- 2022-01-28 01:52:33
@article{a6733874-1624-48c1-87db-95112e5f4b0f, abstract = {{For the first time, we report experimentally and theoretically that nitroaromatic compounds, 2,4-dinitrobenzenethiol and 4-chloro-2-nitrobenzenethiol, on silver sols can be selectively reduced to 2-amino-4-nitrobenzenethiol and 2-amino-4-chlorobenzenethiol simply by irradiating with a visible light in ambient conditions, and the selective photoreduction is a very facile process. The results of quantum chemical calculations are in good agreement with our experimental data. Copyright (c) 2012 John Wiley & Sons, Ltd.}}, author = {{Xia, Lixin and Hu, Xinhu and Sun, Mengtao and Li, Jushi and Yang, Donghui and Wang, Xiaofang and Xu, Hongxing}}, issn = {{1097-4555}}, keywords = {{2; 4-dinitrobenzenethiol; 4-chloro-2-nitrobenzenethiol; silver colloids; surface-enhanced Raman scattering spectroscopy; selective photoreduction}}, language = {{eng}}, number = {{8}}, pages = {{1024--1028}}, publisher = {{John Wiley & Sons Inc.}}, series = {{Journal of Raman Spectroscopy}}, title = {{Selective reduction of nitroaromatic compounds on silver nanoparticles by visible light}}, url = {{http://dx.doi.org/10.1002/jrs.3143}}, doi = {{10.1002/jrs.3143}}, volume = {{43}}, year = {{2012}}, }