Skip to main content

Lund University Publications

LUND UNIVERSITY LIBRARIES

Selective reduction of nitroaromatic compounds on silver nanoparticles by visible light

Xia, Lixin ; Hu, Xinhu ; Sun, Mengtao ; Li, Jushi ; Yang, Donghui ; Wang, Xiaofang and Xu, Hongxing LU (2012) In Journal of Raman Spectroscopy 43(8). p.1024-1028
Abstract
For the first time, we report experimentally and theoretically that nitroaromatic compounds, 2,4-dinitrobenzenethiol and 4-chloro-2-nitrobenzenethiol, on silver sols can be selectively reduced to 2-amino-4-nitrobenzenethiol and 2-amino-4-chlorobenzenethiol simply by irradiating with a visible light in ambient conditions, and the selective photoreduction is a very facile process. The results of quantum chemical calculations are in good agreement with our experimental data. Copyright (c) 2012 John Wiley & Sons, Ltd.
Please use this url to cite or link to this publication:
author
; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
2, 4-dinitrobenzenethiol, 4-chloro-2-nitrobenzenethiol, silver colloids, surface-enhanced Raman scattering spectroscopy, selective photoreduction
in
Journal of Raman Spectroscopy
volume
43
issue
8
pages
1024 - 1028
publisher
John Wiley & Sons Inc.
external identifiers
  • wos:000307550100010
  • scopus:84865172776
ISSN
1097-4555
DOI
10.1002/jrs.3143
language
English
LU publication?
yes
id
a6733874-1624-48c1-87db-95112e5f4b0f (old id 3059769)
date added to LUP
2016-04-01 14:39:54
date last changed
2022-01-28 01:52:33
@article{a6733874-1624-48c1-87db-95112e5f4b0f,
  abstract     = {{For the first time, we report experimentally and theoretically that nitroaromatic compounds, 2,4-dinitrobenzenethiol and 4-chloro-2-nitrobenzenethiol, on silver sols can be selectively reduced to 2-amino-4-nitrobenzenethiol and 2-amino-4-chlorobenzenethiol simply by irradiating with a visible light in ambient conditions, and the selective photoreduction is a very facile process. The results of quantum chemical calculations are in good agreement with our experimental data. Copyright (c) 2012 John Wiley & Sons, Ltd.}},
  author       = {{Xia, Lixin and Hu, Xinhu and Sun, Mengtao and Li, Jushi and Yang, Donghui and Wang, Xiaofang and Xu, Hongxing}},
  issn         = {{1097-4555}},
  keywords     = {{2; 4-dinitrobenzenethiol; 4-chloro-2-nitrobenzenethiol; silver colloids; surface-enhanced Raman scattering spectroscopy; selective photoreduction}},
  language     = {{eng}},
  number       = {{8}},
  pages        = {{1024--1028}},
  publisher    = {{John Wiley & Sons Inc.}},
  series       = {{Journal of Raman Spectroscopy}},
  title        = {{Selective reduction of nitroaromatic compounds on silver nanoparticles by visible light}},
  url          = {{http://dx.doi.org/10.1002/jrs.3143}},
  doi          = {{10.1002/jrs.3143}},
  volume       = {{43}},
  year         = {{2012}},
}