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The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine

Nilsson, Jessica LU ; Colbran, Stephen B. ; Behrens, Ulrich ; Rehder, Dieter and Nordlander, Ebbe LU (2012) In Inorganica Chimica Acta 392. p.490-493
Abstract
Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Vanadium, Vanadyl cation, Reduction, Ascidians
in
Inorganica Chimica Acta
volume
392
pages
490 - 493
publisher
Elsevier
external identifiers
  • wos:000308696200071
  • scopus:84865745221
ISSN
0020-1693
DOI
10.1016/j.ica.2012.04.041
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
6d3acc03-af8d-4ea6-b0c6-c3cabf3151b2 (old id 3190087)
date added to LUP
2016-04-01 13:52:01
date last changed
2022-01-27 21:32:45
@article{6d3acc03-af8d-4ea6-b0c6-c3cabf3151b2,
  abstract     = {{Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.}},
  author       = {{Nilsson, Jessica and Colbran, Stephen B. and Behrens, Ulrich and Rehder, Dieter and Nordlander, Ebbe}},
  issn         = {{0020-1693}},
  keywords     = {{Vanadium; Vanadyl cation; Reduction; Ascidians}},
  language     = {{eng}},
  pages        = {{490--493}},
  publisher    = {{Elsevier}},
  series       = {{Inorganica Chimica Acta}},
  title        = {{The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine}},
  url          = {{http://dx.doi.org/10.1016/j.ica.2012.04.041}},
  doi          = {{10.1016/j.ica.2012.04.041}},
  volume       = {{392}},
  year         = {{2012}},
}