Resonant Auger spectroscopy in solid alkali nitrates as a probe of nuclear motion in the core-excited NO3- anion
(2003) In Chemical Physics Letters 368(1-2). p.125-131- Abstract
- We investigate the interplay between electronic and nuclear relaxation of the core-excited NO3 anion in solid LiNO3 and NaNO3 by means of the high-resolution X-ray absorption and resonant Auger spectroscopy. It is shown how the relative energy distances between the potential energy surfaces of the intermediate and final states can be mapped using the information on the dispersion of individual participator Auger features upon scanning the photon energy across the resonance. The influence of the cation nature (Li+ or Na+) on the potential surfaces is traced and found to be minimal as a consequence of the rather ionic cation-anion interaction. (C) 2002 Published by Elsevier Science B.V.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/320447
- author
- Preobrajenski, Alexei LU ; Vinogradov, AS ; Molodtsov, SL ; Krasnikov, SA ; Szargan, R and Laubschat, C
- organization
- publishing date
- 2003
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Physics Letters
- volume
- 368
- issue
- 1-2
- pages
- 125 - 131
- publisher
- Elsevier
- external identifiers
-
- wos:000180319900020
- scopus:0037435496
- ISSN
- 0009-2614
- DOI
- 10.1016/S0009-2614(02)01798-0
- language
- English
- LU publication?
- yes
- id
- 26ff702c-a64f-4bf5-92e4-706742c7c341 (old id 320447)
- date added to LUP
- 2016-04-01 16:44:13
- date last changed
- 2022-01-28 21:44:59
@article{26ff702c-a64f-4bf5-92e4-706742c7c341, abstract = {{We investigate the interplay between electronic and nuclear relaxation of the core-excited NO3 anion in solid LiNO3 and NaNO3 by means of the high-resolution X-ray absorption and resonant Auger spectroscopy. It is shown how the relative energy distances between the potential energy surfaces of the intermediate and final states can be mapped using the information on the dispersion of individual participator Auger features upon scanning the photon energy across the resonance. The influence of the cation nature (Li+ or Na+) on the potential surfaces is traced and found to be minimal as a consequence of the rather ionic cation-anion interaction. (C) 2002 Published by Elsevier Science B.V.}}, author = {{Preobrajenski, Alexei and Vinogradov, AS and Molodtsov, SL and Krasnikov, SA and Szargan, R and Laubschat, C}}, issn = {{0009-2614}}, language = {{eng}}, number = {{1-2}}, pages = {{125--131}}, publisher = {{Elsevier}}, series = {{Chemical Physics Letters}}, title = {{Resonant Auger spectroscopy in solid alkali nitrates as a probe of nuclear motion in the core-excited NO3- anion}}, url = {{http://dx.doi.org/10.1016/S0009-2614(02)01798-0}}, doi = {{10.1016/S0009-2614(02)01798-0}}, volume = {{368}}, year = {{2003}}, }