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Self-assembly of chiral bicyclic keto-alcohols into supramolecular helices in the solid state

Sarvary, Ian LU ; Johansson, Maria and Frejd, Torbjörn LU (2002) In CrystEngComm p.146-148
Abstract
The bicyclic keto-alcohol (1S,4R,6S)-bicyclo[2.2.2]octan-6-ol-2-one, (+)-3, self-assembles in the solid state through hydrogen bonds between the alcohol and the carbonyl groups creating supramolecular helices, without the aid of other forces such as pi-pi interactions to stabilise the superstructure. Furthermore, the bicyclic compound (4) although structurally quite different, in relation to (+)-3, also formed supramolecular helix in similar fashion.
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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
CrystEngComm
pages
146 - 148
publisher
Royal Society of Chemistry
external identifiers
  • wos:000176247700001
  • scopus:2942643740
ISSN
1466-8033
DOI
10.1039/b202761e
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
3290ea03-ce76-4d2e-b90f-288b41e724a8 (old id 335248)
date added to LUP
2016-04-01 15:50:30
date last changed
2022-02-27 17:05:43
@article{3290ea03-ce76-4d2e-b90f-288b41e724a8,
  abstract     = {{The bicyclic keto-alcohol (1S,4R,6S)-bicyclo[2.2.2]octan-6-ol-2-one, (+)-3, self-assembles in the solid state through hydrogen bonds between the alcohol and the carbonyl groups creating supramolecular helices, without the aid of other forces such as pi-pi interactions to stabilise the superstructure. Furthermore, the bicyclic compound (4) although structurally quite different, in relation to (+)-3, also formed supramolecular helix in similar fashion.}},
  author       = {{Sarvary, Ian and Johansson, Maria and Frejd, Torbjörn}},
  issn         = {{1466-8033}},
  language     = {{eng}},
  pages        = {{146--148}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{CrystEngComm}},
  title        = {{Self-assembly of chiral bicyclic keto-alcohols into supramolecular helices in the solid state}},
  url          = {{http://dx.doi.org/10.1039/b202761e}},
  doi          = {{10.1039/b202761e}},
  year         = {{2002}},
}