The Transient Response Technique for the Study of Hydrocarbon Oxidation on Metal Oxides: Simulation of the Responses for Various Propene Oxidation Mechanism
(1996) In Catalysis Today 32(1-4). p.11-20- Abstract
- Partial differential equations, describing the consumption of reactants and the formation of products, have been solved numerically for a step change from inert to reactant feed considering different variants of propene oxidation mechanisms. The response features and their dependency on the rate limiting step have been rationalised in terms of conclusions, which can serve as general guidelines for mechanistic interpretation of experimental transients from hydrocarbon oxidation over metal oxides. Though the response pattern is characteristic of the rate limiting step, it is demonstrated that different variants of mechanisms can give identical response features. In that case complementary investigation with other techniques, or more detailed... (More)
- Partial differential equations, describing the consumption of reactants and the formation of products, have been solved numerically for a step change from inert to reactant feed considering different variants of propene oxidation mechanisms. The response features and their dependency on the rate limiting step have been rationalised in terms of conclusions, which can serve as general guidelines for mechanistic interpretation of experimental transients from hydrocarbon oxidation over metal oxides. Though the response pattern is characteristic of the rate limiting step, it is demonstrated that different variants of mechanisms can give identical response features. In that case complementary investigation with other techniques, or more detailed mathematical analysis is necessary. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/35837
- author
- Nilsson, Roland and Andersson, Arne LU
- organization
- publishing date
- 1996
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- oxidation, transient response, simulation, propene, mechanism
- in
- Catalysis Today
- volume
- 32
- issue
- 1-4
- pages
- 11 - 20
- publisher
- Elsevier
- external identifiers
-
- scopus:0007731638
- ISSN
- 0920-5861
- DOI
- 10.1016/S0920-5861(96)00177-0
- language
- English
- LU publication?
- yes
- id
- 5ba185cb-6204-4d90-802b-5714d1e261de (old id 35837)
- date added to LUP
- 2016-04-01 15:46:44
- date last changed
- 2023-09-04 06:26:28
@article{5ba185cb-6204-4d90-802b-5714d1e261de,
abstract = {{Partial differential equations, describing the consumption of reactants and the formation of products, have been solved numerically for a step change from inert to reactant feed considering different variants of propene oxidation mechanisms. The response features and their dependency on the rate limiting step have been rationalised in terms of conclusions, which can serve as general guidelines for mechanistic interpretation of experimental transients from hydrocarbon oxidation over metal oxides. Though the response pattern is characteristic of the rate limiting step, it is demonstrated that different variants of mechanisms can give identical response features. In that case complementary investigation with other techniques, or more detailed mathematical analysis is necessary.}},
author = {{Nilsson, Roland and Andersson, Arne}},
issn = {{0920-5861}},
keywords = {{oxidation; transient response; simulation; propene; mechanism}},
language = {{eng}},
number = {{1-4}},
pages = {{11--20}},
publisher = {{Elsevier}},
series = {{Catalysis Today}},
title = {{The Transient Response Technique for the Study of Hydrocarbon Oxidation on Metal Oxides: Simulation of the Responses for Various Propene Oxidation Mechanism}},
url = {{http://dx.doi.org/10.1016/S0920-5861(96)00177-0}},
doi = {{10.1016/S0920-5861(96)00177-0}},
volume = {{32}},
year = {{1996}},
}