Bis(benzimidazolyl)amine copper complexes with a synthetic 'histidine brace' structural motif relevant to polysaccharide monooxygenases
(2014) In Inorganica Chimica Acta 422. p.152-157- Abstract
- Reaction of Cu2+ salts with the benzimidazole-N-methylated bis[(1-methyl-2-benzimidazolyl)ethyl]amine ligand 2BB results in either bi- or monometallic complexes. Spectroscopic and solid state characterization reveals either square pyramidal or trigonal bipyramidal coordination geometries around the cupric ions. In [{2BBCu(mu-F)}(2)](BF4)(2), the dicopper structure is determined by the bridging nature of the fluoro ligands, which complement the T-shape arrangement of N-3 donors provided by 2BB to define a square pyramidal (or capped distorted tetrahedral) coordination geometry. The monocopper complexes 2BBCuCl(2) and [2BBCu(H2O)(2)](OTf)(2) are characterized by a trigonal bipyramidal geometry both in solution and in the solid state. In all... (More)
- Reaction of Cu2+ salts with the benzimidazole-N-methylated bis[(1-methyl-2-benzimidazolyl)ethyl]amine ligand 2BB results in either bi- or monometallic complexes. Spectroscopic and solid state characterization reveals either square pyramidal or trigonal bipyramidal coordination geometries around the cupric ions. In [{2BBCu(mu-F)}(2)](BF4)(2), the dicopper structure is determined by the bridging nature of the fluoro ligands, which complement the T-shape arrangement of N-3 donors provided by 2BB to define a square pyramidal (or capped distorted tetrahedral) coordination geometry. The monocopper complexes 2BBCuCl(2) and [2BBCu(H2O)(2)](OTf)(2) are characterized by a trigonal bipyramidal geometry both in solution and in the solid state. In all complexes, the T-shape N-3 donor set of 2BB is analogous to the coordination environment of the copper ions provided by a 'histidine brace' and an additional histidine imidazole in the active site of polysaccharide monooxygenases. (C) 2014 Elsevier B. V. All rights reserved. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/4783728
- author
- Castillo, Ivan ; Neira, Andrea C. ; Nordlander, Ebbe LU and Zeglio, Erica
- organization
- publishing date
- 2014
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Copper complexes, Benzimidazoles, X-ray crystal structures, Tridentate, ligands
- in
- Inorganica Chimica Acta
- volume
- 422
- pages
- 152 - 157
- publisher
- Elsevier
- external identifiers
-
- wos:000343585800023
- scopus:84907991830
- ISSN
- 0020-1693
- DOI
- 10.1016/j.ica.2014.06.027
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- bc7d966d-d95a-4585-8245-cf22130f3db0 (old id 4783728)
- date added to LUP
- 2016-04-01 13:14:30
- date last changed
- 2022-01-27 18:07:38
@article{bc7d966d-d95a-4585-8245-cf22130f3db0,
abstract = {{Reaction of Cu2+ salts with the benzimidazole-N-methylated bis[(1-methyl-2-benzimidazolyl)ethyl]amine ligand 2BB results in either bi- or monometallic complexes. Spectroscopic and solid state characterization reveals either square pyramidal or trigonal bipyramidal coordination geometries around the cupric ions. In [{2BBCu(mu-F)}(2)](BF4)(2), the dicopper structure is determined by the bridging nature of the fluoro ligands, which complement the T-shape arrangement of N-3 donors provided by 2BB to define a square pyramidal (or capped distorted tetrahedral) coordination geometry. The monocopper complexes 2BBCuCl(2) and [2BBCu(H2O)(2)](OTf)(2) are characterized by a trigonal bipyramidal geometry both in solution and in the solid state. In all complexes, the T-shape N-3 donor set of 2BB is analogous to the coordination environment of the copper ions provided by a 'histidine brace' and an additional histidine imidazole in the active site of polysaccharide monooxygenases. (C) 2014 Elsevier B. V. All rights reserved.}},
author = {{Castillo, Ivan and Neira, Andrea C. and Nordlander, Ebbe and Zeglio, Erica}},
issn = {{0020-1693}},
keywords = {{Copper complexes; Benzimidazoles; X-ray crystal structures; Tridentate; ligands}},
language = {{eng}},
pages = {{152--157}},
publisher = {{Elsevier}},
series = {{Inorganica Chimica Acta}},
title = {{Bis(benzimidazolyl)amine copper complexes with a synthetic 'histidine brace' structural motif relevant to polysaccharide monooxygenases}},
url = {{http://dx.doi.org/10.1016/j.ica.2014.06.027}},
doi = {{10.1016/j.ica.2014.06.027}},
volume = {{422}},
year = {{2014}},
}