Quantitative surface structure determination using in situ high-energy SXRD: Surface oxide formation on Pd(100) during catalytic CO oxidation
(2014) In Surface Science 630. p.229-235- Abstract
- We have performed a quantitative structure determination of the (root 5 x root 5) R27 degrees surface oxide, formed on Pd(100) under semi-realistic conditions for catalytic CO oxidation, using in situ high-energy surface X-ray diffraction. We describe the experiment and the extraction of quantitative data in detail. The structural results are in agreement with previous reports of a system consisting of a single layer of PdO(101) formed in pure O-2 on top of Pd(100) and studied under ultra-high vacuum conditions. (C) 2014 The Authors. Published by Elsevier B.V.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/4874959
- author
- organization
- publishing date
- 2014
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- HESXRD, SXRD, Pd, PdO, CO oxidation, Heterogeneous catalysis
- in
- Surface Science
- volume
- 630
- pages
- 229 - 235
- publisher
- Elsevier
- external identifiers
-
- wos:000344435900031
- scopus:84907821422
- ISSN
- 0039-6028
- DOI
- 10.1016/j.susc.2014.08.021
- language
- English
- LU publication?
- yes
- id
- 76948699-32e5-4851-bd58-61e33b68213b (old id 4874959)
- date added to LUP
- 2016-04-01 14:35:45
- date last changed
- 2022-03-22 00:51:14
@article{76948699-32e5-4851-bd58-61e33b68213b, abstract = {{We have performed a quantitative structure determination of the (root 5 x root 5) R27 degrees surface oxide, formed on Pd(100) under semi-realistic conditions for catalytic CO oxidation, using in situ high-energy surface X-ray diffraction. We describe the experiment and the extraction of quantitative data in detail. The structural results are in agreement with previous reports of a system consisting of a single layer of PdO(101) formed in pure O-2 on top of Pd(100) and studied under ultra-high vacuum conditions. (C) 2014 The Authors. Published by Elsevier B.V.}}, author = {{Shipilin, Mikhail and Hejral, Uta and Lundgren, Edvin and Merte, Lindsay and Zhang, Chu and Stierle, Andreas and Ruett, Uta and Gutowski, Olof and Skoglundh, Magnus and Carlsson, Per-Anders and Gustafson, Johan}}, issn = {{0039-6028}}, keywords = {{HESXRD; SXRD; Pd; PdO; CO oxidation; Heterogeneous catalysis}}, language = {{eng}}, pages = {{229--235}}, publisher = {{Elsevier}}, series = {{Surface Science}}, title = {{Quantitative surface structure determination using in situ high-energy SXRD: Surface oxide formation on Pd(100) during catalytic CO oxidation}}, url = {{http://dx.doi.org/10.1016/j.susc.2014.08.021}}, doi = {{10.1016/j.susc.2014.08.021}}, volume = {{630}}, year = {{2014}}, }