Crystal structure of 2-hy-droxy-imino-2-(pyridin-2-yl)-N'-[1-(pyridin-2-yl)ethyl-idene]acetohydrazide.
(2014) In Acta Crystallographica Section E: Structure Reports Online 70(Pt 12). p.584-586- Abstract
- The mol-ecule of the title compound, C14H13N5O2, is approximately planar (r.m.s deviation for all non-H atoms = 0.093 Å), with the planes of the two pyridine rings inclined to one another by 5.51 (7)°. The oxime group is syn to the amide group, probably due to the formation of an intra-molecular N-H⋯N hydrogen bond that forms an S(6) ring motif. In the crystal, mol-ecules are linked by pairs of bifurcated O-H⋯(O,N) hydrogen bonds, forming inversion dimers. The latter are linked via C-H⋯O and C-H⋯N hydrogen bonds, forming sheets lying parallel to (502). The sheets are linked via π-π stacking inter-actions [inter-centroid distance = 3.7588 (9) Å], involving the pyridine rings of inversion-related mol-ecules, forming a three-dimensional... (More)
- The mol-ecule of the title compound, C14H13N5O2, is approximately planar (r.m.s deviation for all non-H atoms = 0.093 Å), with the planes of the two pyridine rings inclined to one another by 5.51 (7)°. The oxime group is syn to the amide group, probably due to the formation of an intra-molecular N-H⋯N hydrogen bond that forms an S(6) ring motif. In the crystal, mol-ecules are linked by pairs of bifurcated O-H⋯(O,N) hydrogen bonds, forming inversion dimers. The latter are linked via C-H⋯O and C-H⋯N hydrogen bonds, forming sheets lying parallel to (502). The sheets are linked via π-π stacking inter-actions [inter-centroid distance = 3.7588 (9) Å], involving the pyridine rings of inversion-related mol-ecules, forming a three-dimensional structure. (Less)
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https://lup.lub.lu.se/record/5041589
- author
- Plutenko, Maxym O ; Lampeka, Rostislav D ; Haukka, Matti and Nordlander, Ebbe LU
- organization
- publishing date
- 2014
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Acta Crystallographica Section E: Structure Reports Online
- volume
- 70
- issue
- Pt 12
- pages
- 584 - 586
- publisher
- International Union of Crystallography
- external identifiers
-
- pmid:25552998
- scopus:84915752090
- pmid:25552998
- ISSN
- 1600-5368
- DOI
- 10.1107/S1600536814025793
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- 3d6218ef-6ba1-4e0e-8c3b-8ebcdcbd2a0f (old id 5041589)
- date added to LUP
- 2016-04-01 13:50:02
- date last changed
- 2022-01-27 21:21:40
@article{3d6218ef-6ba1-4e0e-8c3b-8ebcdcbd2a0f,
abstract = {{The mol-ecule of the title compound, C14H13N5O2, is approximately planar (r.m.s deviation for all non-H atoms = 0.093 Å), with the planes of the two pyridine rings inclined to one another by 5.51 (7)°. The oxime group is syn to the amide group, probably due to the formation of an intra-molecular N-H⋯N hydrogen bond that forms an S(6) ring motif. In the crystal, mol-ecules are linked by pairs of bifurcated O-H⋯(O,N) hydrogen bonds, forming inversion dimers. The latter are linked via C-H⋯O and C-H⋯N hydrogen bonds, forming sheets lying parallel to (502). The sheets are linked via π-π stacking inter-actions [inter-centroid distance = 3.7588 (9) Å], involving the pyridine rings of inversion-related mol-ecules, forming a three-dimensional structure.}},
author = {{Plutenko, Maxym O and Lampeka, Rostislav D and Haukka, Matti and Nordlander, Ebbe}},
issn = {{1600-5368}},
language = {{eng}},
number = {{Pt 12}},
pages = {{584--586}},
publisher = {{International Union of Crystallography}},
series = {{Acta Crystallographica Section E: Structure Reports Online}},
title = {{Crystal structure of 2-hy-droxy-imino-2-(pyridin-2-yl)-N'-[1-(pyridin-2-yl)ethyl-idene]acetohydrazide.}},
url = {{http://dx.doi.org/10.1107/S1600536814025793}},
doi = {{10.1107/S1600536814025793}},
volume = {{70}},
year = {{2014}},
}