Solvent Exchange and Complex Formation Reactions of Pd(II) in Aqueous Solution. Mechanistic Information from High Pressure Studies
(1990) In High Pressure Research 1990(5). p.672-674- Abstract
- High pressure NMR and stopped-flow techniques have been employed to study a series of water exchange and complex formation reactions of Pd(II) outlined in (1) and (2). The volumes of activation show an interesting correlation with the partial molar volume of the entering ligand and underline the operation of an associative substitution mechanism in all cases.
- Abstract (Swedish)
- High pressure NMR and stopped-flow techniques have been employed to study a series of water exchange and complex formation reactions of Pd(II) outlined in (1) and (2). The volumes of activation show an interesting correlation with the partial molar volume of the entering ligand and underline the operation of an associative substitution mechanism in all cases.
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https://lup.lub.lu.se/record/64199487-1433-4ddc-9ea5-acafe15be1fe
- author
- Hellquist, Björn ; Elding, Lars Ivar LU ; Merbach, Andre E. ; Ducommun, Yves ; Helm, Lothar and van Eldik, Rudi
- organization
- publishing date
- 1990
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Solvent exchange, Complex formatioon, Palladium(II), Volume of activation, Associative reactions, High pressure stopped-flow, High pressure NMR, High Pressure NMR, High pressure stopped-Flow, Activation volume, Reaction mechanism, Associative mechanism
- in
- High Pressure Research
- volume
- 1990
- issue
- 5
- pages
- 672 - 674
- publisher
- Taylor & Francis
- external identifiers
-
- scopus:84963435950
- ISSN
- 1477-2299
- DOI
- 10.1080/08957959008246223
- language
- English
- LU publication?
- yes
- id
- 64199487-1433-4ddc-9ea5-acafe15be1fe
- date added to LUP
- 2017-01-08 22:33:45
- date last changed
- 2021-01-03 09:06:48
@article{64199487-1433-4ddc-9ea5-acafe15be1fe, abstract = {{High pressure NMR and stopped-flow techniques have been employed to study a series of water exchange and complex formation reactions of Pd(II) outlined in (1) and (2). The volumes of activation show an interesting correlation with the partial molar volume of the entering ligand and underline the operation of an associative substitution mechanism in all cases.<br/><br/>}}, author = {{Hellquist, Björn and Elding, Lars Ivar and Merbach, Andre E. and Ducommun, Yves and Helm, Lothar and van Eldik, Rudi}}, issn = {{1477-2299}}, keywords = {{Solvent exchange; Complex formatioon; Palladium(II); Volume of activation; Associative reactions; High pressure stopped-flow; High pressure NMR; High Pressure NMR; High pressure stopped-Flow; Activation volume; Reaction mechanism; Associative mechanism}}, language = {{eng}}, number = {{5}}, pages = {{672--674}}, publisher = {{Taylor & Francis}}, series = {{High Pressure Research}}, title = {{Solvent Exchange and Complex Formation Reactions of Pd(II) in Aqueous Solution. Mechanistic Information from High Pressure Studies}}, url = {{http://dx.doi.org/10.1080/08957959008246223}}, doi = {{10.1080/08957959008246223}}, volume = {{1990}}, year = {{1990}}, }